Selenium halide-induced bridge formation in [2.2]paracyclophanes

被引：30

作者：

Sarbu, Laura G. ^{[1
]}

Hopf, Henning ^{[2
]}

Jones, Peter G. ^{[3
]}

Birsa, Lucian M. ^{[1
,2
]}

机构：

[1] Alexandru Ioan Cuza Univ, Dept Chem, RO-700506 Iasi, Romania

[2] Tech Univ Carolo Wilhelmina Braunschweig, Inst Organ Chem, D-38106 Braunschweig, Germany

[3] Tech Univ Carolo Wilhelmina Braunschweig, Inst Inorgan & Analyt Chem, D-38106 Braunschweig, Germany

来源：

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2014年 / 10卷

关键词：

acetylenes; dienes; 2.2]paracyclophane; selenium halides; HETEROCYCLES; TELLURIUM;

D O I：

10.3762/bjoc.10.266

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An addition/elimination sequence of selenium halides to pseudo-geminally bis(acetylene) substituted [2.2]paracyclophanes leads to new bridges with an endo-exo-diene substructure. The reactions have been found to be sensitive to the substitution of the ethynyl group. The formation of dienes with a zig-zag configuration is related to that observed for non-conjugated cyclic diynes of medium ring size.

引用

页码：2550 / 2555

页数：6

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