1H-Imidazol-4(5H)-ones and thiazol-4(5H)-ones as emerging pronucleophiles in asymmetric catalysis

被引：8

作者：

Mielgo, Antonia ^{[1
]}

Palomo, Claudio ^{[1
]}

机构：

[1] Univ Basque Country, Dept Quim Organ 1, Fac Quim, Apdo 1072, San Sebastian 20080, Spain

来源：

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2016年 / 12卷

关键词：

asymmetric catalysis; bifunctional catalysts; 1H-imidazol-4(5H)-ones; pronucleophiles; thiazol-4(5H)-ones; CARBON BOND FORMATION; ENANTIOSELECTIVE MICHAEL ADDITION; AMINO-ACID-DERIVATIVES; STEREOSELECTIVE-SYNTHESIS; 1,4-ADDITION REACTION; GAMMA-ADDITION; SOFT ENOLIZATION; THIOUREA ORGANOCATALYSTS; QUATERNARY STEREOCENTERS; BIOLOGICAL EVALUATION;

D O I：

10.3762/bjoc.12.90

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Asymmetric catalysis represents a very powerful tool for the synthesis of enantiopure compounds. In this context the main focus has been directed not only to the search for new efficient chiral catalysts, but also to the development of efficient pronucleophiles. This review highlights the utility and first examples of 1H-imidazol-4(5H)-ones and thiazol-4(5H)-ones as pronucleophiles in catalytic asymmetric reactions.

引用

页码：918 / 936

页数：19

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