In Situ Nondestructive Identification of Natural Dyes in Ancient Textiles by Reflection Fourier Transform Mid-Infrared (FT-MIR) Spectroscopy

被引:4
作者
De Luca, Eleonora [1 ]
Bruni, Silvia [1 ]
Sali, Diego [2 ]
Guglielmi, Vittoria [1 ]
Belloni, Paolo [2 ]
机构
[1] Univ Milan, Dipartimento Chim, I-20133 Milan, Italy
[2] Bruker Italia Srl, I-20158 Milan, Italy
关键词
Reflection Fourier transform infrared spectroscopy; FT-IR; In situ analysis; Ancient textile dyes; Portable instrumentation; NONINVASIVE DIAGNOSTIC-TECHNIQUE; ARTIFACTS; FLUOROMETRY; PROTEIN; ORCEIN; WOOL; SILK;
D O I
10.1366/14-07635
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
Silk embroideries and cotton grounds of ancient Caucasian (Kaitag) textiles were analyzed in situ by a portable Fourier transform infrared (FT-IR) spectrometer equipped with a reflection module. Differently colored areas were analyzed for the purpose of identifying the dyes fixed on the fibers. The spectra so obtained were elaborated by calculating the corresponding second derivative, and a library search was then performed using a database including the second derivative spectra of a large range of historical dyes and the corresponding undyed fibers. The results presented here suggest that this technique, combined with the library search method, has a good capability of recognizing natural dyes on both types of ancient textile fibers, in an entirely non-destructive way.
引用
收藏
页码:222 / 229
页数:8
相关论文
共 21 条
[1]  
[Anonymous], 2007, Fourier Transform Infrared Spectrometry
[2]   Identification of Natural Dyes on Laboratory-Dyed Wool and Ancient Wool, Silk, and Cotton Fibers Using Attenuated Total Reflection (ATR) Fourier Transform Infrared (FT-IR) Spectroscopy and Fourier Transform Raman Spectroscopy [J].
Bruni, Silvia ;
De Luca, Eleonora ;
Guglielmi, Vittoria ;
Pozzi, Federica .
APPLIED SPECTROSCOPY, 2011, 65 (09) :1017-1023
[3]  
Cardon D., 2007, NATURAL DYES SOURCES
[4]  
Chenciner R., 1993, KAITAG TEXTILE ART D, DOI DOI 10.1016/j.saa.2008.08.006
[5]   In situ fluorimetry: A powerful non-invasive diagnostic technique for natural dyes used in artefacts - Part I. Spectral characterization of orcein in solution, on silk and wool laboratory-standards and a fragment of Renaissance tapestry [J].
Clementi, C. ;
Miliani, C. ;
Romani, A. ;
Favaro, G. .
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2006, 64 (04) :906-912
[6]   In-situ fluorimetry: A powerful non-invasive diagnostic technique for natural dyes used in artefacts Part II. Identification of orcein and indigo in Renaissance tapestries [J].
Clementi, C. ;
Miliani, C. ;
Romani, A. ;
Santamaria, U. ;
Morresi, F. ;
Mlynarska, K. ;
Favaro, G. .
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2009, 71 (05) :2057-2062
[7]   Toward the optical tongue: Flow-through sensing of tannin-protein interactions based on FTIR spectroscopy [J].
Edelmann, A ;
Lendl, B .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (49) :14741-14747
[8]   Identification of dyestuffs in historical textiles: Strong and weak points of a non-invasive approach [J].
Gulmini, M. ;
Idone, A. ;
Diana, E. ;
Gastaldi, D. ;
Vaudan, D. ;
Aceto, M. .
DYES AND PIGMENTS, 2013, 98 (01) :136-145
[9]   Colour symbolism in the folk literature and textile tradition of the Caucasus [J].
Hunt, D ;
Chenciner, R .
OPTICS AND LASER TECHNOLOGY, 2006, 38 (4-6) :458-465
[10]   The application of in situ mid-FTIR fibre-optic reflectance spectroscopy and GC-MS analysis to monitor and evaluate painting cleaning [J].
Kahrim, Kenza ;
Daveri, Alessia ;
Rocchi, Paola ;
de Cesare, Grazia ;
Cartechini, Laura ;
Miliani, Costanza ;
Brunetti, B. G. ;
Sgamellotti, A. .
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2009, 74 (05) :1182-1188