Nontraditional Reactions of Azomethine Ylides: Decarboxylative Three-Component Couplings of α-Amino Acids

被引：203

作者：

Zhang, Chen ^{[1
]}

Seidel, Daniel ^{[1
]}

机构：

[1] Rutgers State Univ, Dept Chem & Chem Biol, Piscataway, NJ 08854 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 06期

基金：

美国国家科学基金会;

关键词：

C-H BOND; ORGANIC-SYNTHESIS; REDOX PROCESS; ISOMERIZATION; NITROGEN; ROUTE; TRANSAMINATION; CYCLOADDITIONS; HETEROCYCLES; MECHANISM;

D O I：

10.1021/ja910719x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New reactions of azomethine ylides with nontraditional dipolarophiles are reported. Azomethine ylides, formed ill situ via decarboxylative condensations of alpha-amino acids with aldehydes, Undergo reactions with naphthols, indoles, alkynes, and nitroalkanes.

引用

页码：1798 / +

页数：3

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