Triamidoamine complexes of scandium, yttrium and the lanthanides

被引：30

作者：

Roussel, P ^{[1
]}

Alcock, NW ^{[1
]}

Scott, P ^{[1
]}

机构：

[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 07期

关键词：

D O I：

10.1039/a708785c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Synthesis of the simple triamidoamine complexes of the group 3 and lanthanide elements is achieved for the first time by reaction of [Li-3(NN'(3))(thf)(3)] [NN'(3) = N(CH2CH2NSiMe3)(3)] with the metal trichlorides; the 'ate' complexes [M(NN'(3))ClLi(thf)(3)] (M = Sc, Y, La) thus produced are converted smoothly to [M(NN'(3))] on sublimation in vacuo.

引用

页码：801 / 802

页数：2