Triamidoamine complexes of scandium, yttrium and the lanthanides

被引：30

作者：

Roussel, P ^{[1
]}

Alcock, NW ^{[1
]}

Scott, P ^{[1
]}

机构：

[1] Univ Warwick, Dept Chem, Coventry CV4 7AL, W Midlands, England

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 07期

关键词：

D O I：

10.1039/a708785c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Synthesis of the simple triamidoamine complexes of the group 3 and lanthanide elements is achieved for the first time by reaction of [Li-3(NN'(3))(thf)(3)] [NN'(3) = N(CH2CH2NSiMe3)(3)] with the metal trichlorides; the 'ate' complexes [M(NN'(3))ClLi(thf)(3)] (M = Sc, Y, La) thus produced are converted smoothly to [M(NN'(3))] on sublimation in vacuo.

引用

页码：801 / 802

页数：2

共 21 条

[1] STRUCTURE OF TRIS(BIS(TRIMETHYLSILYL)AMIDO)NEODYMIUM(III), ND[N(SI(CH3)3)2]3 [J].

ANDERSEN, RA ;

TEMPLETON, DH ;

ZALKIN, A .

INORGANIC CHEMISTRY, 1978, 17 (08) :2317-2319

[2] Rare earth azatrane chemistry: Facile cleavage of THF to give a Y2Li3O cluster [J].

Aspinall, HC ;

Tillotson, MR .

INORGANIC CHEMISTRY, 1996, 35 (08) :2163-&

[3] TRIGONAL-MONOPYRAMIDAL M(III) COMPLEXES OF THE TYPE [M(N3N)] (M = TI, V, CR, MN, FE N3N = [(TBUME2SI)NCH2CH2]3N) [J].

CUMMINS, CC ;

LEE, J ;

SCHROCK, RR ;

DAVIS, WD .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1992, 31 (11) :1501-1503

[4] 3 COORDINATION IN METAL-COMPLEXES [J].

ELLER, PG ;

BRADLEY, DC ;

HURSTHOUSE, MB ;

MEEK, DW .

COORDINATION CHEMISTRY REVIEWS, 1977, 24 (01) :1-95

[5] 3-CO-ORDINATE SCANDIUM(III) AND EUROPIUM(III) - CRYSTAL AND MOLECULAR-STRUCTURES OF THEIR TRISHEXAMETHYLDISILYLAMIDES [J].

GHOTRA, JS ;

HURSTHOUSE, MB ;

WELCH, AJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1973, (18) :669-670

[6] BEYOND NATURES CHIRAL POOL - ENANTIOSELECTIVE CATALYSIS IN INDUSTRY [J].

NUGENT, WA ;

RAJANBABU, TV ;

BURK, MJ .

SCIENCE, 1993, 259 (5094) :479-483

[7] STRUCTURAL CRITERIA FOR THE MODE OF BONDING OF ORGANOACTINIDES AND ORGANOLANTHANIDES AND RELATED-COMPOUNDS [J].

RAYMOND, KN ;

EIGENBROT, CW .

ACCOUNTS OF CHEMICAL RESEARCH, 1980, 13 (08) :276-283

[8] Synthesis and structure of a trigonal monopyramidal Vanadium(III) complex, [(C6F5NCH2CH2)(3)N]V, and the Vanadium(IV) product of its oxidation, {[(C6F5NCH2CH2)(2)N(CH2CH2NHC6F5)]V(O)}(2) [J].

Rosenberger, C ;

Schrock, RR ;

Davis, WM .

INORGANIC CHEMISTRY, 1997, 36 (01) :123-125

[9] Complex of dinitrogen with trivalent uranium [J].

Roussel, P ;

Scott, P .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (05) :1070-1071

[10] Alkoxide and aryloxide derivatives of a (triamidoamine)uranium complex [J].

Roussel, P ;

Hitchcock, PB ;

Tinker, ND ;

Scott, P .

INORGANIC CHEMISTRY, 1997, 36 (25) :5716-5721

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