One-pot electrochemical formation of meso,meso-linked porphyrin arrays

被引：91

作者：

Ogawa, T ^{[1
]}

Nishimoto, Y

Yoshida, N

Ono, N

Osukua, A

机构：

[1] Kyushu Univ, Inst Fundamental Res Organ Chem, Higashi Ku, Fukuoka 81281, Japan

[2] Ehime Univ, Fac Sci, Dept Chem, Matsuyama, Ehime 790, Japan

[3] Kyoto Univ, Grad Sch Sci, Dept Chem, Sakyo Ku, Kyoto 60601, Japan

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 03期

关键词：

D O I：

10.1039/a707653c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electrochemical oxidation of [5,15-bis(3,5-di-tert-butylphenyl)porphyrinato]zinc(II) 1, [5,15-bis(4-methoxycarbonylphenyl)porphyrinato]zinc(II), [5,15-bis(pentafluorophenyl)porphyrinato] zinc(II), or [10-bromo-5,15-diphenylporphyrinato]zinc(II) in benzonitrile using a platinum net as the working electrode afforded the corresponding meso,meso-linked oligomer porphyrin arrays, and up to the octamer porphyrin array could be isolated for 1.

引用

页码：337 / 338

页数：2

共 11 条

[1] Electrosynthesis and characterization of symmetrical and unsymmetrical linear porphyrin dimers and their precursor monomers [J].

Giraudeau, A ;

Ruhlmann, L ;

ElKahef, L ;

Gross, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (12) :2969-2979

[2] Rational approach to the synthesis of meso-meso (5,5') linked bis-porphyrins [J].

Khoury, RG ;

Jaquinod, L ;

Smith, KM .

CHEMICAL COMMUNICATIONS, 1997, (11) :1057-1058

[3] A stepwise electron-transfer relay mimicking the primary charge separation in bacterial photosynthetic reaction center [J].

Osuka, A ;

Marumo, S ;

Mataga, N ;

Taniguchi, S ;

Okada, T ;

Yamazaki, I ;

Nishimura, Y ;

Ohno, T ;

Nozaki, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (01) :155-168

[4] meso,meso-linked porphyrin arrays [J].

Osuka, A ;

Shimidzu, H .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (1-2) :135-137

[5] Sequential electron-transfer relay in diporphyrin-porphyrin-pyromellitimide triads analogous to that in the photosynthetic reaction center [J].

Osuka, A ;

Nakajima, S ;

Okada, T ;

Taniguchi, S ;

Nozaki, K ;

Ohno, T ;

Yamazaki, I ;

Nishimura, Y ;

Mataga, N .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (01) :92-95

[6] One-pot electrochemical generation of a porphyrin dimer with a bis(diphenylphosphonium)acetylene bridge [J].

Ruhlmann, L ;

Giraudeau, A .

CHEMICAL COMMUNICATIONS, 1996, (17) :2007-2008

[7] Porphyrin wheels [J].

Schenning, APHJ ;

Benneker, FBG ;

Geurts, HPM ;

Liu, XY ;

Nolte, RJM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (36) :8549-8552

[8]

SCHUMM JS, 1994, ANGEW CHEM INT EDIT, V33, P1360, DOI 10.1002/anie.199413601

[9] Synthesis and crystal structures of cofacial bischlorin. Octaethylchlorin-based structural models for the special pair in photosynthesis [J].

Senge, MO ;

Kalisch, WW ;

RuhlandtSenge, K .

CHEMICAL COMMUNICATIONS, 1996, (18) :2149-2150

[10] Synthesis of novel porphyrin arrays directly-linked through the meso-carbons [J].

Susumu, K ;

Shimidzu, T ;

Tanaka, K ;

Segawa, H .

TETRAHEDRON LETTERS, 1996, 37 (46) :8399-8402

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