Superhigh-Luminance Ce:YAG Phosphor in Glass and Phosphor-in-Glass Film for Laser Lighting

被引:62
作者
Bao, Shuyang [1 ]
Liang, Yueyuan [1 ]
Wang, Liansheng [1 ]
Wang, Luhan [1 ]
Xu, Li [2 ]
Wang, Yu [2 ]
Liang, Xiaojuan [1 ]
Xiang, Weidong [1 ]
机构
[1] Wenzhou Univ, Coll Chem & Mat Engn, Wenzhou 325035, Peoples R China
[2] Wenzhou Univ, Coll Life & Environm Sci, Wenzhou 325035, Peoples R China
关键词
laser lighting; Y3Al5O12; Ce3+; phosphor in glass; phosphor-in-glass film; TEMPERATURE-DEPENDENCE; THERMAL-CONDUCTIVITY; WHITE LEDS; MICROSTRUCTURE; DIFFUSIVITY; EFFICIENCY; CONVERTER; STABILITY; 2D;
D O I
10.1021/acssuschemeng.2c02657
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
: Solid laser lighting with high photoelectric conversion efficiency and compact size has been increasingly vital in lighting applications. Extensive research has been conducted to obtain highquality color converters for application to high-power and highluminance laser lighting. Currently, Y3Al5O12:Ce3+ phosphor in glass (Ce:PiG) and Y3Al5O12:Ce3+ phosphor-in-glass film (Ce:PiF) possessing high efficiency, low cost, easy fabrication, and controllable chromaticity are becoming the most mainstream research directions. In this study, by modifying the glass particle size and sintering temperature, investigating the relevant host glass, and so forth, highperformance Ce:PiG was developed through a one-step co-sintering technology. It possesses a high internal quantum efficiency, approaching 100% of the original phosphors (92.5%). The luminous efficacy (LE) of the Ce:PiG was 240 lm/W at 2.18 W/mm2 under 450 nm blue laser diode (LD) excitation, which is the best result yet reported. Furthermore, to enhance the laser saturation threshold, the fabricated Ce:PiF relying on a sapphire substrate can withstand an 8 W/mm2 blue incident power density. The obtained sample can even reach an LE of 251.5 lm/W, which is an obvious improvement to Ce:PiG. In addition, the result, an LD module combined with the sample that meets the standard white light source, indicates that this work has good prospects for white laser lighting.
引用
收藏
页码:8105 / 8114
页数:10
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