Eutectic Molecular Liquids Based on Hydrogen Bonding and π-π Interaction for Exfoliating Two-dimensional Materials and Recycling Polymers

被引:47
作者
Yu, Dongkun [1 ]
Mou, Hongyu [1 ,2 ]
Zhao, Xinhui [1 ]
Wang, Yaqing [1 ]
Mu, Tiancheng [1 ]
机构
[1] Renmin Univ China, Dept Chem, Beijing 100872, Peoples R China
[2] Qingdao Univ Sci & Technol, Shandong Key Lab Biochem Anal, Coll Chem & Mol Engn, Qingdao 266042, Shandong, Peoples R China
基金
中国国家自然科学基金;
关键词
2D materials; DSC; eutectic molecular liquids; plastic recycling; polymers; CHOLINE CHLORIDE; BASIS-SETS; SOLVENTS; PLASTICS; HALOGEN;
D O I
10.1002/asia.201900990
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Eutectic molecular liquids (EMLs) based on hydrogen-bonding interaction and pi-pi stacking were prepared. We found that the thermodynamic properties like initial decomposition temperature and glass transition temperature of EMLs are mainly dominated by the hydrogen bond donor, which is beneficial for designing and preparing new EMLs. These new liquid systems could be applied in the field of environmental and material science.
引用
收藏
页码:3350 / 3356
页数:7
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