A chiral diamondoid 3D lanthanum metal-organic framework displaying blue-greenish long lifetime photoluminescence emission

被引：67

作者：

Rodriguez-Dieguez, A. ^{[1
]}

Salinas-Castillo, A. ^{[2
]}

Sironi, A. ^{[3
]}

Seco, J. M. ^{[4
]}

Colacio, E. ^{[1
]}

机构：

[1] Univ Granada, Dept Quim Inorgan, E-18071 Granada, Spain

[2] Univ Miguel Hernandez, Inst Biol Mol & Celular, Alicante 03202, Spain

[3] Univ Milan, Dipartimento Chim Strutturale & Stereochim Inorga, Milan, Italy

[4] Univ Basque Country, Fac Ciencias San Sebastian, Dept Quim Aplicada, San Sebastian 20008, Spain

来源：

CRYSTENGCOMM | 2010年 / 12卷 / 06期

关键词：

COORDINATION POLYMERS; HYDROGEN ADSORPTION; MAGNETIC-PROPERTIES; LUMINESCENCE; COMPLEXES; NETWORKS; STORAGE; DESIGN;

D O I：

10.1039/b919243c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The compound [La(pmtz)(TzC)(H2O)(3)](H2O) (pmtz = 5-(pyrimidyl)-tetrazolato, TzC = 5-carboxylato-tetrazolato) has been prepared under hydrothermal conditions and exhibits a 3D diamondoid network. This three-dimensional metal-organic framework has channels with hosted water molecules inside and shows an intense blue-greenish long lifetime photoluminescence emission at room temperature in the solid state with two lifetime decay values of 0.26 and 27 ms.

引用

页码：1876 / 1879

页数：4

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