Facile synthesis of hierarchical porous WO3 nanofibers having 1D nanoneedles and their functionalization with non-oxidized graphene flakes for selective detection of acetone molecules

被引:43
作者
Choi, Seon-Jin [1 ]
Choi, Chanyong [2 ,3 ]
Kim, Sang-Joon [1 ]
Cho, Hee-Jin [1 ]
Jeon, Seokwoo [2 ,3 ]
Kim, Il-Doo [1 ]
机构
[1] Korea Adv Inst Sci & Technol, Dept Mat Sci & Engn, Taejon 305701, South Korea
[2] Korea Adv Inst Sci & Technol, Dept Mat Sci & Engn, Taejon 305701, South Korea
[3] Korea Adv Inst Sci & Technol, Graphene Res Ctr KI NanoCentury, Taejon 305701, South Korea
关键词
SENSING PROPERTIES; OXIDE NANOWIRES; LUNG-CANCER; DIAGNOSIS; SENSORS; NANOSTRUCTURES; NANOPARTICLES; EXFOLIATION; COMPOSITES;
D O I
10.1039/c4ra13791d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Multiple pore-loaded (1D) WO3 nanofibers (NFs) having 1D nanoneedle branches were successfully synthesized by polystyrenecolloid-template-assisted electrospinning followed by a two-step heat-treatment. Randomly branched WO3 nanoneedles and high porosity effectively facilitated the surface reaction with acetone molecules. In addition, the hierarchical porous WO3 NFs were further functionalized with catalytic non-oxidized graphene (NOGR) flakes, which showed dramatically improved acetone sensing performance. The results demonstrated the high potential for application in the diagnosis of diabetes by breath acetone analysis.
引用
收藏
页码:7584 / 7588
页数:5
相关论文
共 35 条
[1]   From 1D and 2D ZnO nanostructures to 3D hierarchical structures with enhanced gas sensing properties [J].
Alenezi, Mohammad R. ;
Henley, Simon J. ;
Emerson, Neil G. ;
Silva, S. Ravi P. .
NANOSCALE, 2014, 6 (01) :235-247
[2]  
Behl M, 2012, NAT NANOTECHNOL, V7, P810, DOI [10.1038/nnano.2012.194, 10.1038/NNANO.2012.194]
[3]   Fabrication and gas sensing properties of hollow SnO2 hemispheres [J].
Chang, Young-Eun ;
Youn, Doo-Young ;
Ankonina, Guy ;
Yang, Dae-Jin ;
Kim, Ho-Gi ;
Rothschild, Avner ;
Kim, Il-Doo .
CHEMICAL COMMUNICATIONS, 2009, (27) :4019-4021
[4]   Bi-functional co-sensitization of graphene oxide sheets and Ir nanoparticles on p-type Co3O4 nanofibers for selective acetone detection [J].
Choi, Seon-Jin ;
Ryu, Won-Hee ;
Kim, Sang-Joon ;
Cho, Hee-Jin ;
Kim, Il-Doo .
JOURNAL OF MATERIALS CHEMISTRY B, 2014, 2 (41) :7160-7167
[5]   Facile Au catalyst loading on the inner shell of hollow SnO2 spheres using Au-decorated block copolymer sphere templates and their selective H2S sensing characteristics [J].
Choi, Seon-Jin ;
Kim, Minsoo P. ;
Lee, Seo-Jin ;
Kim, Bumjoon J. ;
Kim, Il-Doo .
NANOSCALE, 2014, 6 (20) :11898-11903
[6]   Fast Responding Exhaled-Breath Sensors Using WO3 Hemitubes Functionalized by Graphene-Based Electronic Sensitizers for Diagnosis of Diseases [J].
Choi, Seon-Jin ;
Fuchs, Franz ;
Demadrille, Renaud ;
Grevin, Benjamin ;
Jang, Bong-Hoon ;
Lee, Seo-Jin ;
Lee, Jong-Heun ;
Tuller, Harry L. ;
Kim, Il-Doo .
ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (12) :9061-9070
[7]   Selective Detection of Acetone and Hydrogen Sulfide for the Diagnosis of Diabetes and Halitosis Using SnO2 Nanofibers Functionalized with Reduced Graphene Oxide Nanosheets [J].
Choi, Seon-Jin ;
Jang, Bong-Hoon ;
Lee, Seo-Jin ;
Min, Byoung Koun ;
Rothschild, Avner ;
Kim, Il-Doo .
ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (04) :2588-2597
[8]   Selective Diagnosis of Diabetes Using Pt-Functionalized WO3 Hemitube Networks As a Sensing Layer of Acetone in Exhaled Breath [J].
Choi, Seon-Jin ;
Lee, Inkun ;
Jang, Bong-Hoon ;
Youn, Doo-Young ;
Ryu, Won-Hee ;
Park, Chong Ook ;
Kim, Il-Doo .
ANALYTICAL CHEMISTRY, 2013, 85 (03) :1792-1796
[9]   One-dimensional tungsten oxide growth through a grain-by-grain buildup process [J].
Cui, S. M. ;
Lu, G. H. ;
Mao, S. ;
Yu, K. H. ;
Chen, J. H. .
CHEMICAL PHYSICS LETTERS, 2010, 485 (1-3) :64-68
[10]   The synthesis of metal oxide nanowires by directly heating metal samples in appropriate oxygen atmospheres [J].
Dang, HY ;
Wang, J ;
Fan, SS .
NANOTECHNOLOGY, 2003, 14 (07) :738-741