In situ X-ray spectroscopic characterization techniques for electrocatalysis

被引：14
作者：
Arrigo, Rosa [1 ]
机构：
[1] Univ Salford, Sch Sci Engn & Environm, Manchester M5 2WT, Lancs, England
来源：
CURRENT OPINION IN GREEN AND SUSTAINABLE CHEMISTRY | 2022年 / 34卷
关键词：
ELECTROCHEMICAL REDUCTION; RAMAN-SPECTROSCOPY; OXYGEN EVOLUTION; SOLID CATALYSTS; OXIDATION-STATE; CO2; SURFACE; ELECTROLYSIS;
D O I：
10.1016/j.cogsc.2022.100601
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In this short review, a brief analysis of opportunities and challenges offered by in situ X-ray spectroscopic methods in electrocatalysis will be presented. Moreover, a selection of the most recent contributions of in situ spectroscopies on two reactions will be reported to highlight current understanding on the reaction mechanisms, namely the oxygen evolution reaction (OER) over Ir based electrocatalysts and the CO2 reduction reaction (CO2RR) over Cu.
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页数：10
相关论文
共 53 条
[1]   Dynamics over a Cu-graphite electrode during the gas-phase CO2 reduction investigated by APXPS [J].
Arrigo, Rosa ;
Blume, Raoul ;
Large, Alexander Ian ;
Velasco-Velez, Juan Jesus ;
Haevecker, Michael ;
Knop-Gericke, Axel ;
Held, Georg .
FARADAY DISCUSSIONS, 2022, 236 (00) :126-140
[2]   Dynamics at Polarized Carbon Dioxide-Iron Oxyhydroxide Interfaces Unveil the Origin of Multicarbon Product Formation [J].
Arrigo, Rosa ;
Blume, Raoul ;
Streibel, Verena ;
Genovese, Chiara ;
Roldan, Alberto ;
Schuster, Manfred E. ;
Ampelli, Claudio ;
Perathoner, Siglinda ;
Velez, Juan J. Velasco ;
Haevecker, Michael ;
Knop-Gericke, Axel ;
Schloegl, Robert ;
Centi, Gabriele .
ACS CATALYSIS, 2022, 12 (01) :411-430
[3]  
Arrigo R, 2018, FARADAY DISCUSS, V208, P339, DOI [10.1039/C8FD90014K, 10.1039/c8fd90014k]
[4]   Highlights from Faraday Discussion on Designing Nanoparticle Systems for Catalysis, London, UK, May 2018 [J].
Arrigo, Rosa ;
Logsdail, Andrew J. ;
Torrente-Murciano, Laura .
CHEMICAL COMMUNICATIONS, 2018, 54 (68) :9385-9393
[5]   Evidence for tetranuclear bis-μ-oxo cubane species in molecular iridium-based water oxidation catalysts from XAS analysis [J].
Bartlett, Stuart A. ;
Sackville, Emma V. ;
Gibson, Emma K. ;
Celorrio, Veronica ;
Wells, Peter P. ;
Nachtegaal, Maarten ;
Sheehan, Stafford W. ;
Hintermair, Ulrich .
CHEMICAL COMMUNICATIONS, 2019, 55 (54) :7832-7835
[6]   Thermodynamic explanation of the universal correlation between oxygen evolution activity and corrosion of oxide catalysts [J].
Binninger, Tobias ;
Mohamed, Rhiyaad ;
Waltar, Kay ;
Fabbri, Emiliana ;
Levecque, Pieter ;
Koetz, Ruediger ;
Schmidt, Thomas J. .
SCIENTIFIC REPORTS, 2015, 5
[7]   Oxygen Evolution Reaction Electrocatalysis on Transition Metal Oxides and (Oxy)hydroxides: Activity Trends and Design Principles [J].
Burke, Michaela S. ;
Enman, Lisa J. ;
Batchellor, Adam S. ;
Zou, Shihui ;
Boettcher, Shannon W. .
CHEMISTRY OF MATERIALS, 2015, 27 (22) :7549-7558
[8]   Synchrotron radiation techniques in catalytic science [J].
Catlow, C. Richard A. ;
Wells, Peter ;
Gianolio, Diego .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2020, 22 (34) :18745-18746
[9]   Nature and Distribution of Stable Subsurface Oxygen in Copper Electrodes During Electrochemical CO2 Reduction [J].
Cavalca, Filippo ;
Ferragut, Rafael ;
Aghion, Stefano ;
Eilert, Andre ;
Diaz-Morales, Oscar ;
Liu, Chang ;
Koh, Ai Leen ;
Hansen, Thomas W. ;
Pettersson, Lars G. M. ;
Nilsson, Anders .
JOURNAL OF PHYSICAL CHEMISTRY C, 2017, 121 (45) :25003-25009
[10]   Redesign chemical processes to substitute the use of fossil fuels: A viewpoint of the implications on catalysis [J].
Centi, Gabriele ;
Perathoner, Siglinda .
CATALYSIS TODAY, 2022, 387 :216-223
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