Highly sensitive and selective acetylene sensors based on p-n heterojunction of NiO nanoparticles on flower-like ZnO structures

被引:32
作者
Song, Zihao [1 ]
Chen, Weigen [1 ]
Zhang, He [1 ]
Li, Yanqiong [2 ]
Zeng, Wen [1 ]
Tang, Sirui [1 ]
Zhu, Chengzhi [3 ]
机构
[1] Chongqing Univ, State Key Lab Power Transmiss Equipment & Syst Se, Chongqing 400044, Peoples R China
[2] Chongqing Univ Arts & Sci, Sch Elect & Elect Engn, Chongqing 400030, Peoples R China
[3] State Grid Zhejiang Elect Power Co Ltd, Hangzhou 310000, Zhejiang, Peoples R China
基金
美国国家科学基金会;
关键词
NiO-ZnO; Heterojunction; Gas sensor; Acetylene; GAS-SENSING PERFORMANCE; DOPED ZNO; SNO2; NO2; FABRICATION; NANOCOMPOSITE;
D O I
10.1016/j.ceramint.2019.06.212
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Acetylene (C2H2) gas concentration is a key parameter in transformer monitoring. In current work, the selective acetylene sensors which based on flower-like ZnO structures with NiO nanoparticles were successfully fabricated. The NiO-ZnO composites were synthesized by two-step hydrothermal method. And various of characterization analyses had been applied to the exploration of crystal structure and the p-n heterojunction. According to the systematic gas sensitivity tests, the response of NiO-ZnO (5%) to 50 ppm C2H2 was 15.23 at 200 degrees C whereas the response of pure ZnO was 4.1 in the same condition. In addition, the response value of NiO- ZnO (5%) to 50 ppm C2H2 was 3.6 times to 50 ppm H-2. Such a good gas-sensing property of NiO-ZnO composites is due to p-n heterojunction and high catalytic activity of NiO.
引用
收藏
页码:19635 / 19643
页数:9
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