High-entropy oxides for catalysis: Status and perspectives

被引:71
作者
Gao, Yu [1 ]
Liu, Yuzhi [1 ]
Yu, Haiyang [2 ]
Zou, Donglei [2 ]
机构
[1] Tsinghua Univ, Inst Environm & Ecol, Water Res Ctr, Shenzhen Int Grad Sch, Shenzhen, Guangdong, Peoples R China
[2] Jilin Univ, Key Lab Groundwater Resources & Environm, Minist Educ, Changchun, Jilin, Peoples R China
关键词
High-entropy oxides; Catalysis; Metal oxides; Environmental catalysis; WET-AIR OXIDATION; ENERGY; WATER; DESULFURIZATION; PHOTOCATALYSIS; NANOPARTICLES; MECHANISM; EVOLUTION; GRAPHENE; DESIGN;
D O I
10.1016/j.apcata.2022.118478
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Recently, entropy stabilized catalytic systems have been raised great concerns due to the urgent demand for functional materials aiming to realize chemical catalysis. As one of the significant groups, high entropy oxides (HEOs) with variable structure, controllable chemical composition, and rich functional properties have become the research hotspots. This review briefly introduces the advantages of HEOs in the catalytic system brought by their structural characteristics and fully summarizes recent applications of HEOs in thermal/electro/photo-catalysis and supports. Finally, the future prospects of HEOs in environmental catalysis, such as visible light catalysis, catalytic wet air oxidation (CWAO), and single-atom catalyst supports are proposed, which will provide a general direction for the development and breakthrough of HEOs in related fields.
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页数:13
相关论文
共 99 条
  • [91] Carbon nanotube catalysts for oxidative desulfurization of a model diesel fuel using molecular oxygen
    Zhang, Wei
    Zhang, Hong
    Xiao, Jing
    Zhao, Zhenxia
    Yu, Moxin
    Li, Zhong
    [J]. GREEN CHEMISTRY, 2014, 16 (01) : 211 - 220
  • [92] Dense high-entropy boride ceramics with ultra-high hardness
    Zhang, Yan
    Guo, Wei-Ming
    Jiang, Ze-Bin
    Zhu, Qi-Qi
    Sun, Shi-Kuan
    You, Yang
    Plucknett, Kevin
    Lin, Hua-Tay
    [J]. SCRIPTA MATERIALIA, 2019, 164 (135-139) : 135 - 139
  • [93] Heterogeneous/Homogeneous Mediators for High-Energy-Density Lithium-Sulfur Batteries: Progress and Prospects
    Zhang, Ze-Wen
    Peng, Hong-Jie
    Zhao, Meng
    Huang, Jia-Qi
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2018, 28 (38)
  • [94] Mechanochemical Nonhydrolytic Sol-Gel-Strategy for the Production of Mesoporous Multimetallic Oxides
    Zhang, Zihao
    Yang, Shize
    Hu, Xiaobing
    Xu, Haidi
    Peng, Hanggen
    Liu, Miaomiao
    Thapaliya, Bishnu Prasad
    Jie, Kecheng
    Zhao, Jiahua
    Liu, Jixing
    Chen, Hao
    Leng, Yan
    Lu, Xiuyang
    Fu, Jie
    Zhang, Pengfei
    Dai, Sheng
    [J]. CHEMISTRY OF MATERIALS, 2019, 31 (15) : 5529 - 5536
  • [95] A Hydrothermally Stable Single-Atom Catalyst of Pt Supported on High-Entropy Oxide/Al2O3: Structural Optimization and Enhanced Catalytic Activity
    Zhao, Shuaiqi
    Lin, Jiajin
    Wu, Peng
    Ye, Changchun
    Li, Yifei
    Li, Anqi
    Jin, Xiaojing
    Zhao, Yun
    Chen, Guangxu
    Qiu, Yongcai
    Ye, Daiqi
    [J]. ACS APPLIED MATERIALS & INTERFACES, 2021, 13 (41) : 48764 - 48773
  • [96] Preparation and electrocatalytic properties of (FeCrCoNiAl0.1)Ox high-entropy oxide and NiCo-(FeCrCoNiAl0.1)Ox heterojunction films
    Zhao, Shuqin
    Wu, Hengyi
    Yin, Ran
    Wang, Xuening
    Zhong, Huizhou
    Fu, Qiang
    Wan, Wenjin
    Cheng, Tao
    Shi, Ying
    Cai, Guangxu
    Jiang, Changzhong
    Ren, Feng
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2021, 868
  • [97] The Progress of Li-S Batteries-Understanding of the Sulfur Redox Mechanism: Dissolved Polysulfide Ions in the Electrolytes
    Zheng, Dong
    Wang, Gongwei
    Liu, Dan
    Si, Jingyu
    Ding, Tianyao
    Qu, Deyu
    Yang, Xiaoqing
    Qu, Deyang
    [J]. ADVANCED MATERIALS TECHNOLOGIES, 2018, 3 (09):
  • [98] A high-entropy metal oxide as chemical anchor of polysulfide for lithium-sulfur batteries
    Zheng, Yuenan
    Yi, Yikun
    Fan, Meihong
    Liu, Hanyu
    Li, Xue
    Zhang, Rui
    Li, Mingtao
    Qiao, Zhen-An
    [J]. ENERGY STORAGE MATERIALS, 2019, 23 : 678 - 683
  • [99] Zou L.Y., 2007, ADV PHYSICOCHEMICAL, V5, P575, DOI [DOI 10.1007/978-1-59745-173-413, 10.1007/978-1-59745-173-413, DOI 10.1007/978-1-59745-173-4_]