High-entropy oxides for catalysis: Status and perspectives

被引:71
作者
Gao, Yu [1 ]
Liu, Yuzhi [1 ]
Yu, Haiyang [2 ]
Zou, Donglei [2 ]
机构
[1] Tsinghua Univ, Inst Environm & Ecol, Water Res Ctr, Shenzhen Int Grad Sch, Shenzhen, Guangdong, Peoples R China
[2] Jilin Univ, Key Lab Groundwater Resources & Environm, Minist Educ, Changchun, Jilin, Peoples R China
关键词
High-entropy oxides; Catalysis; Metal oxides; Environmental catalysis; WET-AIR OXIDATION; ENERGY; WATER; DESULFURIZATION; PHOTOCATALYSIS; NANOPARTICLES; MECHANISM; EVOLUTION; GRAPHENE; DESIGN;
D O I
10.1016/j.apcata.2022.118478
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Recently, entropy stabilized catalytic systems have been raised great concerns due to the urgent demand for functional materials aiming to realize chemical catalysis. As one of the significant groups, high entropy oxides (HEOs) with variable structure, controllable chemical composition, and rich functional properties have become the research hotspots. This review briefly introduces the advantages of HEOs in the catalytic system brought by their structural characteristics and fully summarizes recent applications of HEOs in thermal/electro/photo-catalysis and supports. Finally, the future prospects of HEOs in environmental catalysis, such as visible light catalysis, catalytic wet air oxidation (CWAO), and single-atom catalyst supports are proposed, which will provide a general direction for the development and breakthrough of HEOs in related fields.
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页数:13
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