High-entropy oxides for catalysis: Status and perspectives

被引:72
|
作者
Gao, Yu [1 ]
Liu, Yuzhi [1 ]
Yu, Haiyang [2 ]
Zou, Donglei [2 ]
机构
[1] Tsinghua Univ, Inst Environm & Ecol, Water Res Ctr, Shenzhen Int Grad Sch, Shenzhen, Guangdong, Peoples R China
[2] Jilin Univ, Key Lab Groundwater Resources & Environm, Minist Educ, Changchun, Jilin, Peoples R China
关键词
High-entropy oxides; Catalysis; Metal oxides; Environmental catalysis; WET-AIR OXIDATION; ENERGY; WATER; DESULFURIZATION; PHOTOCATALYSIS; NANOPARTICLES; MECHANISM; EVOLUTION; GRAPHENE; DESIGN;
D O I
10.1016/j.apcata.2022.118478
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Recently, entropy stabilized catalytic systems have been raised great concerns due to the urgent demand for functional materials aiming to realize chemical catalysis. As one of the significant groups, high entropy oxides (HEOs) with variable structure, controllable chemical composition, and rich functional properties have become the research hotspots. This review briefly introduces the advantages of HEOs in the catalytic system brought by their structural characteristics and fully summarizes recent applications of HEOs in thermal/electro/photo-catalysis and supports. Finally, the future prospects of HEOs in environmental catalysis, such as visible light catalysis, catalytic wet air oxidation (CWAO), and single-atom catalyst supports are proposed, which will provide a general direction for the development and breakthrough of HEOs in related fields.
引用
收藏
页数:13
相关论文
共 50 条
  • [1] High-entropy oxides for catalysis: Status and perspectives
    Gao, Yu
    Liu, Yuzhi
    Yu, Haiyang
    Zou, Donglei
    Applied Catalysis A: General, 2022, 631
  • [2] High-entropy oxides for catalysis: A diamond in the rough
    Pan, Yingtong
    Liu, Ji-Xuan
    Tu, Tian-Zhe
    Wang, Wenzhong
    Zhang, Guo-Jun
    CHEMICAL ENGINEERING JOURNAL, 2023, 451
  • [3] High-entropy fluorite oxides
    Gild, Joshua
    Samiee, Mojtaba
    Braun, Jeffrey L.
    Harrington, Tyler
    Vega, Heidy
    Hopkins, Patrick E.
    Vecchio, Kenneth
    Luo, Jian
    JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2018, 38 (10) : 3578 - 3584
  • [4] General Synthesis of High-Entropy Oxides and Carbon-Supported High-Entropy Oxides by Mechanochemistry
    Gao, Ying
    Tian, Xicai
    Niu, Qiang
    Zhang, Pengfei
    CHEMSUSCHEM, 2025, 18 (02)
  • [5] Recent status and challenging perspective of high entropy oxides for chemical catalysis
    Wang, Yi
    Mi, Jinxing
    Wu, Zhong-Shuai
    CHEM CATALYSIS, 2022, 2 (07): : 1624 - 1656
  • [6] Charge Transport in High-Entropy Oxides
    Skubida, Wojciech
    Jaworski, Daniel
    Mielewczyk-Gryn, Aleksandra
    Wachowski, Sebastian
    Miruszewski, Tadeusz
    Cichy, Kacper
    Swierczek, Konrad
    Gazda, Maria
    JOURNAL OF PHYSICAL CHEMISTRY C, 2023, 127 (29): : 14534 - 14544
  • [7] Physicochemical Properties of High-entropy Oxides
    Ma, Yue
    Chen, Yichuan
    Sun, Mengtao
    Zhang, Yun
    CHEMICAL RECORD, 2023, 23 (02):
  • [8] High-Entropy Oxides for Rechargeable Batteries
    Ran, Biao
    Li, Huanxin
    Cheng, Ruiqi
    Yang, Zhaohui
    Zhong, Yi
    Qin, Yonghong
    Yang, Chao
    Fu, Chaopeng
    ADVANCED SCIENCE, 2024, 11 (25)
  • [9] On the synthesis and formability of high-entropy oxides
    Kandage, Manjula M.
    Marszewski, Michal
    JOURNAL OF MATERIALS SCIENCE, 2024, 59 (35) : 16618 - 16628
  • [10] Activation of partial metal sites in high-entropy oxides for enhancing thermal and electrochemical catalysis
    Mi, Jinxing
    Chen, Xiaoping
    Ding, Yajun
    Zhang, Liangzhu
    Ma, Jun
    Kang, Hui
    Wu, Xianhong
    Liu, Yuefeng
    Chen, Jianjun
    Wu, Zhong-Shuai
    CHINESE JOURNAL OF CATALYSIS, 2023, 48 : 235 - 246