Chemistry - Clipping the carbon-carbon bond

被引:31
作者
Crabtree, RH [1 ]
机构
[1] Yale Univ, Dept Chem, New Haven, CT 06520 USA
关键词
D O I
10.1038/35044164
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
The bonds between two carbon atoms tend to be hard to break. But careful manipulation of the starting material can make the process remarkably easy.
引用
收藏
页码:415 / 416
页数:2
相关论文
共 6 条
[1]   Recent advances in C-F bond activation [J].
Burdeniuc, J ;
Jedlicka, B ;
Crabtree, RH .
CHEMISCHE BERICHTE-RECUEIL, 1997, 130 (02) :145-154
[2]   THE ORGANOMETALLIC CHEMISTRY OF ALKANES [J].
CRABTREE, RH .
CHEMICAL REVIEWS, 1985, 85 (04) :245-269
[3]  
CRABTREE RH, 2001, ORGANOMETALLIC CHEM, P149
[4]   The first observation and kinetic evaluation of a single step metal insertion into a C-C bond [J].
Gandelman, M ;
Vigalok, A ;
Konstantinovski, L ;
Milstein, D .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (40) :9848-9849
[5]   A PCN ligand system. Exclusive C-C activation with rhodium(I) and C-H activation with platinum(II) [J].
Gandelman, M ;
Vigalok, A ;
Shimon, LJW ;
Milstein, D .
ORGANOMETALLICS, 1997, 16 (18) :3981-3986
[6]   Iridium PCP pincer complexes: highly active and robust catalysts for novel homogeneous aliphatic dehydrogenations [J].
Jensen, CM .
CHEMICAL COMMUNICATIONS, 1999, (24) :2443-2449