Construction of a three-fold parallel interpenetration network and bilayer structure based on copper(II) and trimesic acid

被引：86

作者：

Chen, Wen-Xian

Wu, Shu-Ting

Long, La-Sheng ^{[1
]}

Huang, Rong-Bin

Zheng, Lan-Sun

机构：

[1] Xiamen Univ, State Key Lab Phys Chem Solid Surface, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China

[2] Xiamen Univ, Dept Chem, Coll Chem & Chem Engn, Xiamen 361005, Peoples R China

来源：

CRYSTAL GROWTH & DESIGN | 2007年 / 7卷 / 06期

关键词：

D O I：

10.1021/cg070119k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Solvothermal reactions of Cu(NO3)(2)center dot 3H(2)O with trimesic acid (H3BTC) at different pH conditions yield two coordination polymers of [Cu-3(BTC)(2)(H2O)(3)(NH3)(4)](n)center dot 2nH(2)O (1) and [Cu-4(BTC)(2)(OH)(2)(H2O)(2)(NH3)(4)](n) (2). Crystal structural analysis reveals that complex 1 exhibits a three-fold parallel interpenetration network and complex 2 shows a two-dimensional bilayer structure. Crystal data are orthorhombic, space group Pbcn, a = 11.242(3) angstrom, b = 16.963(4) angstrom, c = 13.898(4) angstrom, Z = 4 for 1 and monoclinic, space group C2/c, a = 18.887(4) angstrom, b = 10.761(2) angstrom, c = 14.488(3) angstrom, beta = 126.100(3)degrees, Z = 4 for 2.

引用

页码：1171 / 1175

页数：5

共 69 条

[1] OXIDATION REACTION OF [(CU(HPZ)2CL)2](HPZ = PYRAZOLE) - SYNTHESIS OF THE TRINUCLEAR COPPER(II) HYDROXO COMPLEXES [CU3(OH)(PZ)3(HPZ)2CL2].SOLV (SOLV = H2O OR TETRAHYDROFURAN) - FORMATION, MAGNETIC-PROPERTIES, AND X-RAY CRYSTAL-STRUCTURE OF [CU3(OH)(PZ)3(PY)2CL2].PY (PY = PYRIDINE) [J].

ANGARONI, M ;

ARDIZZOIA, GA ;

BERINGHELLI, T ;

LAMONICA, G ;

GATTESCHI, D ;

MASCIOCCHI, N ;

MORET, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (11) :3305-3309

[2]

[Anonymous], SADABS VERSION 2 05

[3] An unusual three-dimensional coordination network formed by parallel polycatenation of two-fold interpenetrated (6,3) layers based on a novel three-connecting ligand [J].

Banfi, S ;

Carlucci, L ;

Caruso, E ;

Ciani, G ;

Proserpio, DM .

CRYSTAL GROWTH & DESIGN, 2004, 4 (01) :29-32

[4] Interpenetrating and non-interpenetrating 3-dimensional coordination polymer frameworks from multiple building blocks [J].

Bradshaw, D ;

Rosseinsky, MJ .

SOLID STATE SCIENCES, 2005, 7 (12) :1522-1532

[5]

*BRUK AN INSTR, 2000, SHELXTL 6 10

[6] SYNTHESIS AND RELATION BETWEEN MAGNETISM AND STRUCTURE OF A TRINUCLEAR COPPER(II) HYDROXO COMPLEX [CU3OHL3(CIO4)]CIO4 AND A HEXANUCLEAR COPPER(II) OXO COMPLEX [CU3OL'3(CIO4)]2 (LH=3-(PHENYLIMINO)BUTANONE 2-OXIME, L'H=1,2-DIPHENYL-2-(METHYLIMINO)ETHANONE 1-OXIME) [J].

BUTCHER, RJ ;

OCONNOR, CJ ;

SINN, E .

INORGANIC CHEMISTRY, 1981, 20 (02) :537-545

[7] Syntheses and characterizations of copper(II) polymeric complexes constructed from 1,2,4,5-benzenetetracarboxylic acid [J].

Cao, R ;

Shi, Q ;

Sun, DF ;

Hong, MC ;

Bi, WH ;

Zhao, YJ .

INORGANIC CHEMISTRY, 2002, 41 (23) :6161-6168

[8] Self-assembly of novel co-ordination polymers containing polycatenated molecular ladders and intertwined two-dimensional tilings [J].

Carlucci, L ;

Ciani, G ;

Proserpio, DM .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (11) :1799-1804

[9] CRYSTAL-STRUCTURE AND MAGNETIC-PROPERTIES OF TETRAKIS(CYCLOHEXYLAMINE)DI-MU-HYDROXO-DICOPPER(II) PERCHLORATE - 1ST EXAMPLE OF A ROOF-SHAPED HYDROXO-BRIDGED COPPER(II) DIMER [J].

CHARLOT, MF ;

JEANNIN, S ;

JEANNIN, Y ;

KAHN, O ;

LUCRECEABAUL, J ;

MARTINFRERE, J .

INORGANIC CHEMISTRY, 1979, 18 (06) :1675-1681

[10] Synthesis and structure of a new 3D porous Cu(II)-benzene-1,3,5-tricarboxylate coordination polymer, [Cu2(OH)(BTC)(H2O)]n•2nH2O [J].

Chen, JX ;

Yu, T ;

Chen, ZX ;

Xiao, HP ;

Zhou, GQ ;

Weng, LH ;

Tu, B ;

Zhao, DY .

CHEMISTRY LETTERS, 2003, 32 (07) :590-591

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