Photo-curable organically modified silicate-phosphate alternating copolymer for photonics applications

被引：5

作者：

Takahashi, Masahide ^{[1
,2
]}

Suzuki, Masaru ^{[2
]}

Miyagawa, Yuya ^{[2
]}

Ihara, Rie ^{[1
,2
]}

Tokuda, Yomei ^{[2
]}

Yoko, Toshinobu ^{[2
]}

Nemoto, Takashi ^{[2
]}

Isoda, Seiji ^{[2
]}

机构：

[1] Osaka Prefecture Univ, Dept Mat Sci, Grad Sch Engn, Osaka 5998531, Japan

[2] Kyoto Univ, Inst Chem Res, Kyoto 6110011, Japan

来源：

JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY | 2010年 / 54卷 / 03期

关键词：

Photonics materials; Alternating copolymer; Oxo polymer; Organic-inorganic hybrid materials; Organic dye; Rare earth ion; Photo-cure; Soft lithography; Plasmonics; Acid-base reaction; Solventless condensation; LOW-MELTING GLASSES;

D O I：

10.1007/s10971-010-2197-6

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Photo-curable vinyl modified silicate-phosphate alternating copolymers were prepared by a direct condensation of organochlorosilane and organophosphoric acid in a solvent-free condition. The obtained copolymers have complete alternating copolymer structure of silicate and phosphate unit, where the main oxo chain consist of -(Si-O-P-O) (n) -network. They exhibited an excellent solubility of ionic species such as ionic organic dyes. It was also demonstrated the photo-reduction of Au+ ions to form Au nano particles for plasmonics applications. Micro patterns were also fabricated by soft lithographic processes. These results indicate that the photo-curable alternating copolymers are one of promising materials for advanced optical information processing devices.

引用

页码：319 / 324

页数：6

共 17 条

[1]

JOHNSON SG, 2002, PHOTONIC CRYSTALS RO, pCH1

[2] Rewritable Holographic Structures Formed in Organic-Inorganic Hybrid Materials by Photothermal Processing [J].

Kakiuchida, Hiroshi ;

Takahashi, Masahide ;

Tokuda, Yomei ;

Yoko, Toshinobu .

ADVANCED FUNCTIONAL MATERIALS, 2009, 19 (16) :2569-2576

[3] Synthesis and characteristics of curable siloxane-based organic-inorganic hybrid materials modified with vinyl and isopropenoxy [J].

Kang, Eun-Seok ;

Takahashi, Masahide ;

Tokuda, Yomei ;

Yoko, Toshinobu .

JOURNAL OF MATERIALS RESEARCH, 2006, 21 (05) :1286-1293

[4] Wavelength dependence of thermo-optic coefficient of organically modified SiO2-ZrO2 hybrid films [J].

Kang, Eun-Seok ;

Takahashi, Masahide ;

Tokuda, Yomei ;

Yoko, Toshinobu .

APPLIED PHYSICS LETTERS, 2006, 89 (13)

[5]

KLEY EB, 2004, MICROOPICS, pCH1

[6] Quantum information - An integrated light circuit [J].

Kwiat, Paul G. .

NATURE, 2008, 453 (7193) :294-295

[7] Organic-inorganic hybrid material of phenyl-modified polysilicophosphate prepared through nonaqueous acid-base reaction [J].

Mizuno, M ;

Takahashi, M ;

Tokuda, Y ;

Yoko, T .

CHEMISTRY OF MATERIALS, 2006, 18 (08) :2075-2080

[8] Substituent effect on the formation of organically-modified silicate-phosphate alternating copolymer through nonaqueous acid-base reaction [J].

Mizuno, Megumi ;

Takahashi, Masahide ;

Tokuda, Yomei ;

Yoko, Toshinobu .

JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2007, 44 (01) :47-52

[9] Structure and water durability of tin(II) organosilicophosphate glasses prepared by nonaqueous acid-base reactions [J].

Mizuno, Megumi ;

Takahashi, Masahide .

JOURNAL OF MATERIALS RESEARCH, 2006, 21 (07) :1798-1806

[10] Formation dynamics of gold nanoparticles in poly(vinylpyrrolidone) and other protective agent solutions [J].

Nakazato, Yuta ;

Taniguchi, Kazuya ;

Ono, Shunichi ;

Eitoku, Takeshi ;

Katayama, Kenji .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2009, 11 (43) :10064-10072

← 1 2 →