Studies on electrooxidation of 3-picoline to nicotinic acid

被引:0
|
作者
Zhang, YM [1 ]
Zhang, HB [1 ]
Cao, XJ [1 ]
Wang, D [1 ]
Ji, CZ [1 ]
机构
[1] Jilin Univ, Coll Chem, Changchun 130023, Peoples R China
来源
关键词
3-picoline; electrooxidation; nicotinic acid;
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In an electrolytical cell with cation exchange membrane, the electrooxidatione reactions of 3-picoline on Pt or PbO2/Ti electrodes were examined with steady state polarization curves. It was found that PbO2/Ti electrode possesses electrocatalysis activity for synthesizing nicotinic acid. The effects of various factors on current efficiency were also examined by the product analysis with HPLC.
引用
收藏
页码:509 / 512
页数:4
相关论文
共 12 条
  • [1] [Anonymous], [No title captured]
  • [2] CHARLES JP, 1981, ALDRICH LIB INFRARED, P1339
  • [3] Chen K., 1996, EXPT DESIGN ANAL, P94
  • [4] GUPTA PN, 1988, J INDIAN CHEM SOC, V65, P633
  • [5] JIAO DK, 1996, CHEM PRODUCTION TECH, P10
  • [6] LI FM, 1996, FINE CHEM, V13, P30
  • [7] LI GX, 1984, MED IND, P1
  • [8] TOOMEY JE, 1991, Patent No. 5002621
  • [9] WANG GX, 1997, ORGANIC ELECTROSYNTH, P40
  • [10] WANG ZD, 1994, NATURAL GAS CHEM, V19, P33