Fabrication of Cu(In, Ga)Se2 thin film solar cell absorbers from electrodeposited bilayers

被引:4
作者
Oda, Yusuke [1 ]
Matsubayashi, Masakazu [1 ]
Minemoto, Takashi [1 ]
Takakura, Hideyuki [1 ]
机构
[1] Ritsumeikan Univ, Coll Sci & Engn, Kusatsu 5258577, Japan
关键词
Cu(In; Ga)Se-2; Electrodeposition; Bilayers; Solar cell;
D O I
10.1016/j.cap.2009.11.022
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
CuInSe2 (CIS) and Cu(In, Ga)Se-2 (CIGS) films as solar cell absorbers have been fabricated from electrodeposited (ED) In-Se/CIS and CIS/CuGaSe2 (CGS) bilayers, respectively Firstly, In-Se/CIS bilayers were intermixed by annealing at 600 degrees C for 10 min and it followed that OS films with large grains and controlled compositional ratios were realized CIS solar cells using these films showed around 2 2% efficiency Next. CIS/CGS bilayers were annealed at 600 degrees C for 60 min for intermixing Here, oxygen-free CGS films prepared from Cu-Ga-Se solution added Li2SO4 as the supporting electrolyte were used because Ga-O compound formed in ED-CGS films worked as the defects As the results. around 2 9% efficiency CIGS solar cell using the films was realized Especially. 29 7 mA/cm(2) and 36 1 mA/cm(2) high short-circuit current density were obtained in the CIS and CIGS solar cells, respectively These Jesuits indicate that ED-bilayers technique is useful to realize low-cost and high efficiency solar cell (C) 2009 Elsevier B V All rights reserved
引用
收藏
页码:S146 / S149
页数:4
相关论文
共 8 条
[1]   12.3% efficient CuIn1-xGaxSe2-based device from electrodeposited precursor [J].
Bhattacharya, RN ;
Wiesner, H ;
Berens, TA ;
Matson, J ;
Keane, J ;
Ramanathan, K ;
Swartzlander, A ;
Mason, A ;
Noufi, RN .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (04) :1376-1379
[2]   15.4% CuIn1-xGaxSe2-based photovoltaic cells from solution-based precursor films [J].
Bhattacharya, RN ;
Hiltner, JF ;
Batchelor, W ;
Contreras, MA ;
Noufi, RN ;
Sites, JR .
THIN SOLID FILMS, 2000, 361 :396-399
[3]   Single bath electrodeposition of CuInSe2 and Cu(In,Ga)Se2 for thin film photovoltaic cells [J].
Calixto, ME ;
Dobson, KD ;
McCandless, BE ;
Birkmire, RW .
Conference Record of the Thirty-First IEEE Photovoltaic Specialists Conference - 2005, 2005, :378-381
[4]   Stabilization of Manufacturing Process of CIGS Solar Cell with Treatment of CIGS Surface by In and S Containing Solution [J].
Hashimoto, Y. ;
Nishiwaki, S. ;
Negami, T. ;
Wada, T. .
JAPANESE JOURNAL OF APPLIED PHYSICS, 2000, 39 (01) :415-417
[5]  
HASHIMOTO Y, 2001, P 17 EUR PV SOL EN C, P22
[6]   Electrodeposition of crack-free CuGaSe2 thin films from single bath [J].
Oda, Yusuke ;
Minemoto, Takashi ;
Takakura, Hideyuki .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2008, 155 (05) :H292-H295
[7]  
Ramdani O., 2006, P 21 EUROPEAN PHOTOV, P1866
[8]   19.9%-efficient ZnO/CdS/CuInGaSe2 solar cell with 81.2% fill factor [J].
Repins, Ingrid ;
Contreras, Miguel A. ;
Egaas, Brian ;
DeHart, Clay ;
Scharf, John ;
Perkins, Craig L. ;
To, Bobby ;
Noufi, Rommel .
PROGRESS IN PHOTOVOLTAICS, 2008, 16 (03) :235-239