Blocking Polysulfides and Facilitating Lithium-Ion Transport: Polystyrene Sulfonate@HKUST-1 Membrane for Lithium-Sulfur Batteries

被引:81
作者
Guo, Yi [1 ]
Sun, Minghao [2 ]
Liang, Hongqing [3 ]
Ying, Wen [1 ]
Zeng, Xianqing [2 ]
Ying, Yulong [1 ]
Zhou, Shudong [2 ]
Liang, Chengdu [2 ]
Lin, Zhan [2 ]
Peng, Xinsheng [1 ]
机构
[1] Zhejiang Univ, Coll Chem & Biochem Engn, State Key Lab Silicon Mat, Sch Mat Sci & Engn, Hangzhou 310027, Zhejiang, Peoples R China
[2] Zhejiang Univ, Coll Chem & Biochem Engn, Zhejiang Prov Key Lab Adv Chem Engn Manufacture T, Hangzhou 310027, Zhejiang, Peoples R China
[3] Univ Texas San Antonio, Dept Chem, One UTSA Circle, San Antonio, TX 78249 USA
关键词
fast lithium transportation; low polysulfide permeability; PSS@HKUST-1 separator; high efficient lithium-sulfur batteries; high loading electrode; METAL-ORGANIC FRAMEWORK; LI-S BATTERIES; PERFORMANCE; STORAGE; INTERLAYER; CATHODE; IMPACT;
D O I
10.1021/acsami.8b11042
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Minimizing the shuttle effect of polysulfides (PS) is crucial for practical applications of lithium-sulfur (Li-S) batteries. However, the trade-off between effective suppression of the shuttle effect and fast redox reaction kinetics is inevitable for separator-based Li-S batteries. Herein, via a self-confined solid-conversion process, we develop a polystyrene sulfonate (PSS)-threaded well-intergrown HKUST-1 (Cu-3(BTC)(2)) (BTC: 1,3,5-benzene-tricarboxylic acid)-coated Celgard separator (PSS@HKUST-1/Celgard, PHC) for high-performance Li-S batteries. The PHC membrane favors the interception and accommodation of long-chain PS. Notably, enormous sulfonate groups of the three-dimensional PSS networks in PSS@HKUST-1 membrane significantly facilitate lithium-ion transport, which guarantee fast redox kinetics. The PHC separator demonstrates efficient inhibition of PS (i.e., 4 orders of magnitude lower in PS permeation rate) with fast Li+ transportation (i.e., 71% higher in ionic conductivity) than the Celgard separator. When applying the PHC membrane in Li-S batteries with conventional sulfur/super P carbon cathode, highly reversible capacity with an average fading rate of 0.05% per cycle is maintained for 500 cycles at 0.5 C, excellent rate performance up to 5 C, and high areal capacity over 7 mA h cm(-2) are also achieved. This work paves a new way for addressing the trade-off between suppressing the PS shuttle effect and fast kinetic reaction for separator-based Li-S batteries.
引用
收藏
页码:30451 / 30459
页数:9
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