The effect of promoters and additives on removing SO2 at TiO2 catalyst with plasma

被引:0
|
作者
Kim, Heejoon
Han, Jun
Sakaguchi, Yuhei
Minami, Wataru
Sadakata, Masayoshi
机构
[1] Toyohashi Univ Technol, Dept Ecol Engn, Toyohashi, Aichi 4418580, Japan
[2] Kogakuin Univ, Dept Environm Chem Engn, Hachioji, Tokyo 1920015, Japan
关键词
additives; catalyst; conversion; plasma; promoters; SO2;
D O I
10.1252/jcej.40.123
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
With more stringent environmental regulations or acts being implemented, the research on developing a desulfurization/denitrification technology with high efficiency and cost performance becomes very urgent. In this paper, TiO2 catalyst with the addition of different promoters and additives were tested in a laboratory scale plasma reactor. Promoters are V2O5 and K2O-V2O5, and additives are H2O and H2O2, respectively. The experimental results indicate that the promoters (V2O5 and K2O-V2O5) are considerably effective in promoting the activity of TiO2 catalyst in the presence of plasma, which causes the SO, oxidation rate to increase. Meanwhile, K2O-V2O5 (K-promoter) is found to be a better promoter than V2O5. Except for promoters, the additives (H2O, H2O2) also have an important impact on SO2 oxidation in the case of simultaneously using plasma and TiO2 catalyst.
引用
收藏
页码:123 / 127
页数:5
相关论文
共 50 条
  • [1] The synergetic effect of plasma and catalyst on simultaneous removal of SO2 and NOx
    Han, Jun
    Kim, Heejoon
    Sakaguchi, Yuhei
    Cheol-ho, Kim
    Yao, Hong
    ASIA-PACIFIC JOURNAL OF CHEMICAL ENGINEERING, 2010, 5 (03) : 441 - 446
  • [2] Enhancement of the SO2 resistance of Mn/TiO2 SCR catalyst by Eu modification: A mechanism study
    Liu, Jian
    Guo, Rui-tang
    Li, Ming-yuan
    Sun, Peng
    Liu, Shu-ming
    Pan, Wei-guo
    Liu, Shuai-wei
    Sun, Xiao
    FUEL, 2018, 223 : 385 - 393
  • [3] Poisoning mechanism of the coexistence K and SO2 on the deNOx of MnO2/TiO2 catalyst at low temperature
    Liu, Yafang
    Wang, Jiaxin
    Zhu, Baozhong
    Zhou, Xinjian
    Zhou, Jialiang
    Li, Fan
    Sun, Yunlan
    PROCESS SAFETY AND ENVIRONMENTAL PROTECTION, 2023, 174 : 135 - 144
  • [4] The enhanced SCR performance and SO2 resistance of Mn/TiO2 catalyst by the modification with Nb: A mechanistic study
    Sun, Peng
    Huang, Shu-xian
    Guo, Rui-tang
    Li, Ming-yuan
    Liu, Shu-ming
    Pan, Wei-guo
    Fu, Zai-guo
    Liu, Shuai-wei
    Sun, Xiao
    Liu, Jian
    APPLIED SURFACE SCIENCE, 2018, 447 : 479 - 488
  • [5] Promotional effect of CuO loading on the catalytic activity and SO2 resistance of MnOx/TiO2 catalyst for simultaneous NO reduction and Hg0 oxidation
    Yang, Zequn
    Li, Hailong
    Liu, Xi
    Li, Pu
    Yang, Jianping
    Lee, Po-Heng
    Shih, Kaimin
    FUEL, 2018, 227 : 79 - 88
  • [6] Preparation and characterization of Zr(SO4)2/TiO2 catalyst
    Huang, Xin
    Gu, Zhenggui
    Sun, Hao
    JOURNAL OF APPLIED BIOMATERIALS & FUNCTIONAL MATERIALS, 2016, 14 : S41 - S45
  • [7] Reaction mechanism of elemental mercury oxidation to HgSO4 during SO2/SO3 conversion over V2O5/TiO2 catalyst
    Yang, Yingju
    Liu, Jing
    Wang, Zhen
    Yu, Yingni
    PROCEEDINGS OF THE COMBUSTION INSTITUTE, 2021, 38 (03) : 4317 - 4325
  • [8] Non-thermal plasma and catalyst system for simultaneously oxidizing SO2 and NOx
    Kim, Heejoon
    Han, Jun
    Sakaguchi, Yuhei
    Minami, Wataru
    Wang, Guanghui
    PROCEEDINGS OF THE 6TH INTERNATIONAL SYMPOSIUM ON COAL COMBUSTION, 2007, : 453 - 458
  • [9] Non-thermal plasma and catalyst system for simultaneously oxidizing SO2 and NOx
    Han, Shizhong
    Zhang, Qiang
    Chen, Zhiqiong
    ADVANCES IN CHEMICAL, MATERIAL AND METALLURGICAL ENGINEERING, PTS 1-5, 2013, 634-638 : 864 - 868
  • [10] Impact of SO2 on elemental mercury oxidation over CeO2-TiO2 catalyst
    Li, Hailong
    Wu, Chang-Yu
    Li, Ying
    Li, Liqing
    Zhao, Yongchun
    Zhang, Junying
    CHEMICAL ENGINEERING JOURNAL, 2013, 219 : 319 - 326