Copper-catalyzed N-formylation of amines with CO2 under ambient conditions

被引：78

作者：

Zhang, Suqi ^{[1
,2
]}

Mei, Qingqing ^{[2
]}

Liu, Hangyu ^{[2
]}

Liu, Huizhen ^{[2
]}

Zhang, Zepeng ^{[1
]}

Han, Buxing ^{[2
]}

机构：

[1] China Univ Geosci, Sch Mat Sci & Technol, Beijing 100083, Peoples R China

[2] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China

来源：

RSC ADVANCES | 2016年 / 6卷 / 38期

基金：

中国国家自然科学基金;

关键词：

CARBON-DIOXIDE; REDUCTION; CONVERSION; HYDROSILYLATION; TRANSFORMATION; HYDROGENATION; HYDROSILANES; METHANOL;

D O I：

10.1039/c6ra05199e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We carried out work on N-formylation of amines with CO2 and PhSiH3 to produce formamides catalyzed by a copper complex. It was found that the Cu(OAc)(2)-bis(diphenylphosphino)ethane (dppe) catalytic system was very efficient for these kind of reactions at room temperature and 1 atm CO2 with only 0.1 mol% catalyst loading.

引用

页码：32370 / 32373

页数：4

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