Dynamic Spacer Installation for Multirole Metal-Organic Frameworks: A New Direction toward Multifunctional MOFs Achieving Ultrahigh Methane Storage Working Capacity

被引：168

作者：

Chen, Cheng-Xia ^{[1
]}

Wei, Zhang-Wen ^{[1
]}

Jiang, Ji-Jun ^{[1
]}

Zheng, Shao-Ping ^{[1
]}

Wang, Hai-Ping ^{[1
]}

Qu, Qian-Feng ^{[1
]}

Cao, Chen-Chen ^{[1
]}

Fenske, Dieter ^{[1
]}

Su, Cheng-Yong ^{[1
]}

机构：

[1] Sun Yat Sen Univ, Sch Chem, Lehn Inst Funct Mat, MOE Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Guangdong, Peoples R China

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2017年 / 139卷 / 17期

关键词：

FUNCTIONAL-GROUPS; GAS-ADSORPTION;

D O I：

10.1021/jacs.7b01320

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A robust Zr-MOF (LIFM-28) containing replaceable coordination sites for additional spacer installation has been employed to demonstrate a swing- or multirole strategy for multifunctional MOFs. Through reversible installation/uninstallation of two types of spacers with different lengths and variable functional groups, different tasks can be accomplished using the same parent MOF. An orthogonal optimizing method is applied with seven shorter (L1-7) and six longer (L8-13) spacers to tune the functionalities, achieving multipurpose switches among gas separation, catalysis, click reaction, luminescence, and particularly, ultrahigh methane storage working capacity at 5-80 bar and 298 K.

引用

页码：6034 / 6037

页数：4

共 19 条

[1] Stepwise pillar insertion into metal-organic frameworks: a sequential self-assembly approach
Burnett, Brandon J.
Choe, Wonyoung
[J]. CRYSTENGCOMM, 2012, 14 (19): : 6129 - 6131
[2] Precise Modulation of the Breathing Behavior and Pore Surface in Zr-MOFs by Reversible Post-Synthetic Variable-Spacer Installation to Fine-Tune the Expansion Magnitude and Sorption Properties
Chen, Cheng-Xia
Wei, Zhangwen
Jiang, Ji-Jun
Fan, Yan-Zhong
Zheng, Shao-Ping
Cao, Chen-Chen
Li, Yu-Hao
Fenske, Dieter
Su, Cheng-Yong
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (34) : 9932 - 9936
[3] Multiple Functional Groups of Varying Ratios in Metal-Organic Frameworks
Deng, Hexiang
Doonan, Christian J.
Furukawa, Hiroyasu
Ferreira, Ricardo B.
Towne, John
Knobler, Carolyn B.
Wang, Bo
Yaghi, Omar M.
[J]. SCIENCE, 2010, 327 (5967) : 846 - 850
[4] Metal-metalloporphyrin frameworks: a resurging class of functional materials
Gao, Wen-Yang
Chrzanowski, Matthew
Ma, Shengqian
[J]. CHEMICAL SOCIETY REVIEWS, 2014, 43 (16) : 5841 - 5866
[5] Postsynthetic Modification: A Versatile Approach Toward Multifunctional Metal-Organic Frameworks
Garibay, Sergio J.
Wang, Zhenqiang
Tanabe, Kristine K.
Cohen, Seth M.
[J]. INORGANIC CHEMISTRY, 2009, 48 (15) : 7341 - 7349
[6] Methane storage in metal-organic frameworks
He, Yabing
Zhou, Wei
Qian, Guodong
Chen, Banglin
[J]. CHEMICAL SOCIETY REVIEWS, 2014, 43 (16) : 5657 - 5678
[7] Luminescent metal-organic frameworks for chemical sensing and explosive detection
Hu, Zhichao
Deibert, Benjamin J.
Li, Jing
[J]. CHEMICAL SOCIETY REVIEWS, 2014, 43 (16) : 5815 - 5840
[8] High Methane Storage Working Capacity in Metal-Organic Frameworks with Acrylate Links
Jiang, Juncong
Furukawa, Hiroyasu
Zhang, Yue-Biao
Yaghi, Omar M.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (32) : 10244 - 10251
[9] Porous metal-organic frameworks with Lewis basic nitrogen sites for high-capacity methane storage
Li, Bin
Wen, Hui-Min
Wang, Hailong
Wu, Hui
Yildirim, Taner
Zhou, Wei
Chen, Banglin
[J]. ENERGY & ENVIRONMENTAL SCIENCE, 2015, 8 (08) : 2504 - 2511
[10] THERMODYNAMICS OF MIXED-GAS ADSORPTION
MYERS, AL
PRAUSNITZ, JM
[J]. AICHE JOURNAL, 1965, 11 (01) : 121 - +

← 1 2 →