Synthesis and crystal structure of [Li(THF)4]Cu2Br4

被引：4

作者：

Margraf, Gunter ^{[1
]}

Bolte, Michael ^{[1
]}

Wagner, Matthias ^{[1
]}

Lerner, Hans-Wolfram ^{[1
]}

机构：

[1] Univ Frankfurt, Inst Anorgan Chem, D-60438 Frankfurt, Germany

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2007年 / 37卷 / 07期

关键词：

coordination chemistry; copper; redox chemistry; X-ray structure analysis;

D O I：

10.1007/s10870-007-9204-y

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The mixed-valence compound [Li(THF)(4)]Cu2Br4 was synthesized in a redox reaction from 1,4-dihydroxynaphthalene, CuBr2 and LiNtBuSiMe(3) in THF. X-ray quality crystals of [Li(THF)(4)]Cu2Br4 (monoclinic, P2(1)/c) are obtained from the mother liquor at ambient temperature. In the solid state, infinite chains of anionic [Cu2Br4](-) units are established. These chains are separated by [Li(THF)(4)](+) cations.

引用

页码：503 / 506

页数：4

共 6 条

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