Intra-/inter-molecular synergistic inhibition effect of sulfonate surfactant and 2-benzothiazolethiol on carbon steel corrosion in 3.5% NaCl solution

被引:50
作者
Zhu, Hailin [1 ]
Li, Xiaofen [1 ]
Lu, Xiaomeng [1 ]
Chen, Xiaojie [1 ]
Li, Jun [1 ]
Han, Xinghua [1 ]
Ma, Xuemei [1 ]
Hu, Zhiyong [1 ]
机构
[1] North Univ China, Sch Chem Engn & Technol, Taiyuan 030051, Peoples R China
基金
中国国家自然科学基金;
关键词
Intra-/inter-molecular synergism; Carbon steel; NaCl solution; Electrochemical techniques; Theoretical studies; MILD-STEEL; GEMINI SURFACTANT; IONIC LIQUIDS; ACID; PERFORMANCE; COPPER; DERIVATIVES; MECHANISM; TWEEN-80; BEHAVIOR;
D O I
10.1016/j.corsci.2021.109291
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A sulfonate surfactant (CHT) was synthesized, reacted with 2-benzothiazolethiol (MBT) to obtain CHMT to investigate the intramolecular synergistic inhibition effect of CHT and MBT. Meanwhile, a mixture of CHT and MBT in a 1:1 mol ratio (CHT + MBT) was used to investigate the intermolecular synergistic inhibition effect of CHT and MBT. The results from electrochemical experiment and theoretical studies indicated that CHMT and CHT + MBT strongly inhibited the corrosion of carbon steel in 3.5 % NaCl solution compared to MBT or CHT, revealing intramolecular and intermolecular synergistic action between CHT and MBT. Additionally, the mechanisms of intramolecular and intermolecular synergistic effects were proposed.
引用
收藏
页数:13
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