Resonant Inelastic X-ray Scattering of Molybdenum Oxides and Sulfides

被引：19

作者：

Thomas, Rowena ^{[1
,2
]}

Kas, Josh ^{[3
]}

Glatzel, Pieter ^{[4
]}

Al Samarai, Mustafa ^{[6
]}

de Groot, Frank M. F. ^{[6
]}

Mori, Roberto Alonso ^{[4
,5
]}

Kavcic, Matjaz

Zitnik, Matjaz ^{[7
]}

Bucar, Klemen ^{[7
]}

Rehr, John J. ^{[3
,7
]}

Tromp, Moniek ^{[2
]}

机构：

[1] Univ Southampton, Southampton SO17 1BJ, Hants, England

[2] Tech Univ Munich, Catalysis Res Ctr, Dept Chem, D-85748 Garching, Germany

[3] Univ Washington, Dept Phys, Seattle, WA 98195 USA

[4] European Synchrotron Radiat Facil, F-38043 Grenoble 9, France

[5] SLAC Natl Accelerator Lab, LCLS, Menlo Pk, CA 94025 USA

[6] Univ Utrecht, Debye Inst Nanomat Sci, NL-3584 CG Utrecht, Netherlands

[7] Jozef Stefan Inst, SI-1001 Ljubljana, Slovenia

来源：

JOURNAL OF PHYSICAL CHEMISTRY C | 2015年 / 119卷 / 05期

基金：

英国工程与自然科学研究理事会;

关键词：

SPECTROSCOPY; CATALYSTS; SPECTRA; XANES; EDGE;

D O I：

10.1021/jp509376q

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Molybdenum oxides and sulfides were studied using resonant inelastic X-ray scattering (RIXS). The 2p(3/2)3d Mo RIXS planes show a rich structure with considerably more spectral information than in conventional X-ray absorption near edge structure (XANES) spectroscopy. The spectra were simulated using FEFF9 giving generally good agreement and detailed electronic information can be derived. The reference materials serve as a starting point for detailed electronic and geometric investigations of a broad range of compounds. In particular, this can provide insights in the properties and performance of unknown and changing materials like those in catalysis.

引用

页码：2419 / 2426

页数：8

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