Three-dimensional microporous graphene decorated with lithium

被引:1
作者
Iacobucci, Marco [1 ]
Di Bernardo, Iolanda [1 ]
Christian, Meganne [2 ]
Morandi, Vittorio [2 ]
Ripanti, Francesca [1 ]
Postorino, Paolo [1 ]
Mariani, Carlo [1 ]
Betti, Maria Grazia [1 ]
机构
[1] Sapienza Univ, Dept Phys, Rome, Italy
[2] CNR IMM, Bologna, Italy
基金
欧盟地平线“2020”;
关键词
microporous graphene; Raman; XPS; lithium; WALLED CARBON NANOTUBES; NANOPOROUS GRAPHENE; RAMAN-SPECTROSCOPY; VAPOR-DEPOSITION; GRAPHITE; CATHODE; ANODE; OXIDE; AREA; SUPERCAPACITORS;
D O I
10.1088/1361-6528/aad3f5
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Three-dimensional (3D) graphene-based architectures can combine the two-dimensional properties of graphene with the high surface-to-volume ratio required for a large variety of technological applications. We present a spectro-microscopy study of stable microporous 3D few-layer graphene structures with a very low density of defects/edges and of unsaturated bonds, as deduced by Raman and core level photoemission spectroscopy. These qualities make these interconnected graphene networks ideal candidates to accommodate lithium adatoms, with a high density of Li per unit volume and a Li uptake per C atom higher than the value observed for graphite, as confirmed by core level photoemission spectroscopy.
引用
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页数:8
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