Iron(III) porphyrin supported on S and N co-doped graphene quantum dot as an efficient photocatalyst for aerobic oxidation of alcohols under visible light irradiation

被引：54

作者：

Mahyari, Mojtaba ^{[1
]}

Bide, Yasamin ^{[2
]}

Gavgani, Jaber Nasrollah ^{[3
]}

机构：

[1] Malek Ashtar Univ Technol, Elites Adv Res Ctr, POB 16765-3454, Tehran, Iran

[2] Shahid Beheshti Univ, Fac Chem, GC, POB 19396-4716, Tehran, Iran

[3] Amirkabir Univ Technol, Dept Polymer Engn & Color Technol, POB 15875-4413, Tehran, Iran

来源：

APPLIED CATALYSIS A-GENERAL | 2016年 / 517卷

基金：

美国国家科学基金会;

关键词：

Graphene quantum dots; Photocatalyst; Aerobic oxidation; Iron(III) porphyrin; ONE-STEP SYNTHESIS; SELECTIVE OXIDATION; GOLD NANOPARTICLES; BENZYLIC ALCOHOLS; CARBON NANOTUBES; ELECTROCATALYTIC ACTIVITY; NITROGEN; CATALYSTS; WATER; GREEN;

D O I：

10.1016/j.apcata.2016.03.010

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this study, we report the synthesis and impressive performance of Fe(III)tetra(4-sulfonatophenyl)porphyrins (FeTSPP) supported on S and N co-doped graphene quantum dots (S, N: GQDs) as efficient, recyclable, and noble metal free heterogeneous photocatalyst for the selective aerobic oxidation of alcohols to the corresponding carbonyl compounds. It was found that FeTSPP@S, N: GQDs photocatalyst represents a novel chemical function for efficient visible light catalyzed aerobic alcohol oxidation with good conversions and selectivity in water as a green solvent at room temperature. We envision that FeTSPP@S, N: GQDs provide a promising candidate for the development of highly efficient, recyclable, and industrially applicable photocatalyst in fine chemical production with high activity. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：100 / 109

页数：10

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