13-tungstoborate stabilized by an organostannoxane hexamer

被引：34
作者：
Reinoso, Santiago [1 ]
Dickman, Michael H. [1 ]
Matei, Marius F. [1 ]
Kortz, Ulrich [1 ]
机构：
[1] Jacobs Univ Bremen, Sch Sci & Engn, D-28725 Bremen, Germany
来源：
INORGANIC CHEMISTRY | 2007年 / 46卷 / 11期
关键词：
D O I：
10.1021/ic7004437
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The novel dimethyltin-containing polyanion [{(CH3)(2)Sn}(6)(OH)(2)O-2-(H2BW13O46)(2)](12-) (1) is composed of two [H2BW13O46](9-) clusters linked by an unprecedented planar, hexameric [{(CH3)(2)Sn}(6)(OH)(2)O-2](8+) organostannoxane moiety, representing the first X-ray structural characterization of a molecular hybrid organic-inorganic tungstoborate and of the elusive [HnBW13O46]((11-n)-) species.
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收藏
页码：4383 / 4385
页数：3
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