Preparation and crystal structure of the azavinylidene derivative Cp2Ti(CH=CH2)(N=CPh2) derived from the thermally generated titanaallene intermediate [Cp2Ti=C=CH2]

被引：0

作者：

Beckhaus, R ^{[1
]}

Wagner, M ^{[1
]}

Wang, R ^{[1
]}

机构：

[1] Rhein Westfal TH Aachen, Inst Anorgan Chem, D-52056 Aachen, Germany

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1998年 / 624卷 / 02期

关键词：

titanium; vinylidene complexes; azavinylidene compounds; crystal structure;

D O I：

10.1002/(SICI)1521-3749(199802)624:2<277::AID-ZAAC277>3.0.CO;2-T

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title complex 4 was synthesized by reaction of Benzophenonimin with the titanaallene fragment [Cp-2*Ti=C=CH2] (3). Complex 4 was characterized by H-1 and C-13 NMR spectra and by X-ray structure analysis, respectively.

引用

页码：277 / 280

页数：4

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Preparation and crystal structure of the azavinylidene derivative Cp*2Ti(CH=CH2)(N=CPh2) derived from the thermally generated titanaallene intermediate [Cp*2Ti=C=CH2]

Preparation and crystal structure of the azavinylidene derivative Cp2Ti(CH=CH2)(N=CPh2) derived from the thermally generated titanaallene intermediate [Cp2Ti=C=CH2]