Distinctive rheological and temporal viscoelastic behaviour of alkali-activated fly ash/slag pastes: A comparative study with cement paste

This paper presents the results of the investigation on the fundamental differences in the viscoelasticity between alkali-activated fly ash/slag materials (AAMs) and cement pastes. The effects of the precursor and the activator on the rheological behaviour of AAM pastes were studied. Given the specific precursor, the activator viscosity significantly affected the AAM paste viscosity. The high viscous activator increased the plastic viscosity of AAM pastes by 4-8 times higher than that of cement paste and drastically decreased the yield stress due to viscous effects and weak colloidal interactions. Temporal changes in viscoelasticity showed that the negligible colloidal interactions between particles in AAM paste made the system non-percolated until the initial setting. This resulted in very different viscoelastic behaviour compared to the one from the well-percolated network in cement paste. Considering all results obtained in this study, the paper describes the short-term evolution of the AAM paste from the fresh condition to the initial setting.