Folding directed N-oxidation of oligopyridine-dicarboxamide strands and hybridization of oxidized oligomers

被引：84
作者：
Dolain, C
Zhan, CL
Léger, JM
Daniels, L
Huc, I
机构：
[1] Inst Europeen Chim & Biol, F-33607 Pessac, France
[2] Lab Pharmacochim, F-33076 Bordeaux, France
[3] Rigaku MSC Inc, The Woodlands, TX 77381 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 08期
关键词：
D O I：
10.1021/ja0424631
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Folding of oligopyridine-dicarboxamides into helices inhibits the N-oxidation of pyridine rings central in the sequence and also much enhances the N-oxidation of pyridine rings peripheral in the sequence. Oligomers N-oxidized at their terminal position show an increased ability to hybridize into double helices. Copyright © 2005 American Chemical Society.
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页码：2400 / 2401
页数：2
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