A highly selective and sensitive benzothiazole-based 'turn-on' fluorescent sensor for Hg2+ ion

被引：21

作者：

Erdemir, Serkan ^{[1
]}

Malkondu, Sait ^{[1
]}

Alici, Onder ^{[1
]}

机构：

[1] Selcuk Univ, Fac Sci, Dept Chem, TR-42031 Konya, Turkey

来源：

COLORATION TECHNOLOGY | 2015年 / 131卷 / 01期

关键词：

NAKED-EYE DETECTION; MERCURY; CHEMOSENSOR; METHYLMERCURY; METALS;

D O I：

10.1111/cote.12122

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A simple benzothiazole-based fluorescent probe (TDA) for the determination of Hg2+ ion in aqueous solutions was synthesised in one step and characterised by H-1 NMR, C-13 NMR, APT, COSY, FTIR, and elemental analysis. TDA shows a significant fluorescence change upon the interaction of Hg2+ ion in DMF-water (v/v=1/1), while only minor changes in fluorescence intensity are observed with 18 other metal ions. Fluorescence enhancement by a factor of 15 is achieved upon selective interaction with Hg2+ ion. The Hg2+ ion detection process is found to be pH dependent; therefore, TDA could be feasible within a pH range of 4.0-7.0.

引用

页码：32 / 37

页数：6

共 36 条

[31] A BODIPY-Based Highly Selective Fluorescent Chemosensor for Hg2+ Ions and Its Application in Living Cell Imaging [J].

Vedamalai, Mani ;

Wu, Shu-Pao .

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2012, 2012 (06) :1158-1163

[32] Simple hydrazide-based fluorescent sensors for highly sensitive and selective optical signaling of Cu2+ and Hg2+ in aqueous solution [J].

Wang, Xianyong ;

Zhao, Jingjing ;

Guo, Chaoxia ;

Pei, Meishan ;

Zhang, Guangyou .

SENSORS AND ACTUATORS B-CHEMICAL, 2014, 193 :157-165

[33] 1-Pyrenecarboxaldehyde thiosemicarbazone: A novel fluorescent molecular sensor towards mercury (II) ion [J].

Wang, Xue Mei ;

Yan, Hua ;

Feng, Xin Lu ;

Chen, Yong .

CHINESE CHEMICAL LETTERS, 2010, 21 (09) :1124-1128

[34] "Naked-eye" colorimetric and "turn-on" fluorometric chemosensors for reversible Hg2+ detection [J].

Wanichacheva, Nantanit ;

Praikaew, Panida ;

Suwanich, Thanapat ;

Sukrat, Kanjarat .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2014, 118 :908-914

[35] Zn2+-Triggered Amide Tautomerization Produces a Highly Zn2+-Selective, Cell-Permeable, and Ratiometric Fluorescent Sensor [J].

Xu, Zhaochao ;

Baek, Kyung-Hwa ;

Kim, Ha Na ;

Cui, Jingnan ;

Qian, Xuhong ;

Spring, David R. ;

Shin, Injae ;

Yoon, Juyoung .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (02) :601-610

[36]

Yong C, 2012, RARE METAL MAT ENG, V41, P1871

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