Detection of AuF by emission spectroscopy in a hollow cathode discharge

被引：20

作者：

Andreev, S ^{[1
]}

BelBruno, JJ ^{[1
]}

机构：

[1] Dartmouth Coll, Dept Chem, Burke Chem Lab, Hanover, NH 03755 USA

来源：

CHEMICAL PHYSICS LETTERS | 2000年 / 329卷 / 5-6期

关键词：

D O I：

10.1016/S0009-2614(00)01052-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The emission spectrum of AuF, produced in a hollow cathode discharge, is recorded over the wavelength range from 350 to 650 nm. By comparison with density functional theory calculations, including relativistic corrections, and using the known spectrum and DFT calculations for the low-lying electronic states of CuF, the three AuF bands are assigned to vibrational transitions involving the lowest energy (1)Sigma (+) and (1)Pi excited states. Spectral assignments differ from those previously reported. (C) 2000 Elsevier Science B.V. All rights reserved.

引用

页码：490 / 494

页数：5

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