Vapor pressure measurements of bis(hydroxyethyl)piperazine and tris(hydroxyethyl)ethylenediamine

被引:13
作者
Abdi, MA [1 ]
Meisen, A [1 ]
机构
[1] Univ British Columbia, Dept Chem & Bioresource Engn, Vancouver, BC V6T 1Z4, Canada
关键词
D O I
10.1021/je970146m
中图分类号
O414.1 [热力学];
学科分类号
摘要
Vapor pressures of bis(hydroxyethyl)piperazine (BHEP) and tris(hydroxyethyl)ethylenediamine (THEED) were measured in the temperature ranges of (412.65 to 507.15) K and (372.55 to 472.35) K using the static and gas saturation techniques, respectively. The experimental data are well represented by the modified Antoine and the integrated Clausius-Clapeyron equations, and their coefficients are reported. The enthalpies of vaporization were found to be (62.76 +/- 5.33) and (89.96 +/- 3.91) kJ/mol for BHEP and THEED, respectively.
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页码:133 / 137
页数:5
相关论文
共 11 条
[1]  
Abdi M.A., 1997, THESIS U BRIT COLUMB
[2]  
BOUBLIK T, 1975, VAPOR PRESSURES PURE
[3]  
DAWODU OF, 1993, P AICHE SPRING NAT M
[4]  
HALL WD, 1981, P 31 ANN L REID GAS, pC1
[5]   MECHANISMS AND KINETICS OF DIETHANOLAMINE DEGRADATION [J].
KENNARD, ML ;
MELSEN, A .
INDUSTRIAL & ENGINEERING CHEMISTRY FUNDAMENTALS, 1985, 24 (02) :129-140
[6]  
MEISEN A, 1982, HYDROCARB PROCESS, V61, P105
[7]  
Ohe S., 1976, COMPUTER AIDED DATA
[8]  
PATTERSON G. N., 1956, Molecular Flow of Gases
[9]  
Stewart E. J, 1991, P 41 ANN LAUR REID G, P60
[10]   MEASUREMENT OF THE VAPOR-PRESSURE OF SEVERAL LOW-VOLATILITY ORGANOCHLORINE CHEMICALS AT LOW-TEMPERATURES WITH A GAS SATURATION METHOD [J].
WANIA, F ;
SHIU, WY ;
MACKAY, D .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1994, 39 (03) :572-577