Asymmetric sequential Au(I)/chiral tertiary amine catalysis: an enone-formation/cyanosilylation sequence to synthesize optically active 3-alkenyloxindoles from diazooxindoles

被引：53
作者：
Zhao, Yu-Lei [1 ]
Cao, Zhong-Yan [1 ]
Zeng, Xing-Ping [1 ]
Shi, Jia-Meng [2 ]
Yu, Yi-Hua [2 ]
Zhou, Jian [1 ,3 ]
机构：
[1] E China Normal Univ, Sch Chem & Mol Engn, Shanghai Key Lab Green Chem & Chem Proc, 3663N,Zhongshan Rd, Shanghai 200062, Peoples R China
[2] E China Normal Univ, Dept Phys, Shanghai Key Lab Magnet Resonance, 3663N, Shanghai 200062, Peoples R China
[3] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, 345 Lingling Lu, Shanghai 200032, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 20期
关键词：
VINYLOGOUS MICHAEL ADDITION; H BOND FUNCTIONALIZATION; ENANTIOSELECTIVE CYANOSILYLATION; MULTICOMPONENT REACTIONS; 3-ALKYLIDENE OXINDOLES; COOPERATIVE CATALYSIS; 3-COMPONENT REACTIONS; CARBENE INSERTION; ACID CATALYSIS; RECYCLE WASTE;
D O I：
10.1039/c6cc00333h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An unprecedented sequential gold-catalyzed enone-formation and bifunctional tertiary amine mediated asymmetric cyanosilylation reaction is developed, allowing the highly enantioselective synthesis of 3-alkenyloxindoles from diazooxindoles, furans and trimethylsilyl cyanide (TMSCN).
引用
收藏
页码：3943 / 3946
页数：4
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