Asymmetric sequential Au(I)/chiral tertiary amine catalysis: an enone-formation/cyanosilylation sequence to synthesize optically active 3-alkenyloxindoles from diazooxindoles

被引：53

作者：

Zhao, Yu-Lei ^{[1
]}

Cao, Zhong-Yan ^{[1
]}

Zeng, Xing-Ping ^{[1
]}

Shi, Jia-Meng ^{[2
]}

Yu, Yi-Hua ^{[2
]}

Zhou, Jian ^{[1
,3
]}

机构：

[1] E China Normal Univ, Sch Chem & Mol Engn, Shanghai Key Lab Green Chem & Chem Proc, 3663N,Zhongshan Rd, Shanghai 200062, Peoples R China

[2] E China Normal Univ, Dept Phys, Shanghai Key Lab Magnet Resonance, 3663N, Shanghai 200062, Peoples R China

[3] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, 345 Lingling Lu, Shanghai 200032, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 20期

关键词：

VINYLOGOUS MICHAEL ADDITION; H BOND FUNCTIONALIZATION; ENANTIOSELECTIVE CYANOSILYLATION; MULTICOMPONENT REACTIONS; 3-ALKYLIDENE OXINDOLES; COOPERATIVE CATALYSIS; 3-COMPONENT REACTIONS; CARBENE INSERTION; ACID CATALYSIS; RECYCLE WASTE;

D O I：

10.1039/c6cc00333h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An unprecedented sequential gold-catalyzed enone-formation and bifunctional tertiary amine mediated asymmetric cyanosilylation reaction is developed, allowing the highly enantioselective synthesis of 3-alkenyloxindoles from diazooxindoles, furans and trimethylsilyl cyanide (TMSCN).

引用

页码：3943 / 3946

页数：4

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