Electrifying interfaces

被引：5
作者：
Marken, F [1 ]
机构：
[1] Univ Loughborough, Dept Chem, Loughborough LE11 3TU, Leics, England
来源：
PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES | 2004年 / 362卷 / 1825期
关键词：
electrochemistry; charged phase boundaries; ion transfer; triple junctions; electrosynthesis; tunnelling;
D O I：
10.1098/rsta.2004.1461
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
Electrochemical processes at electrified or polarized phase boundaries and methods for charging phase boundaries are discussed. An important type of interface, the three-phase junction, is introduced and processes at three-phase junctions are compared with those occurring at two-phase functions. Finally, pairing charged interfaces is considered as a methodology for a more efficient use of electrical energy in microscale electrochemical processes. Chemical processes triggered by currents in the ultimate type of paired electrode system. a tunnel junction, are discussed.
引用
收藏
页码：2611 / 2633
页数：23
相关论文
共 62 条
  • [41] Pletcher D., 1993, IND ELECTROCHEMISTRY
  • [42] Reddy AKN, 2000, MODERN ELECTROCHEM A
  • [43] Conductance of a molecular junction
    Reed, MA
    Zhou, C
    Muller, CJ
    Burgin, TP
    Tour, JM
    [J]. SCIENCE, 1997, 278 (5336) : 252 - 254
  • [44] Rowlinson J. S., 1982, MOL THEORY CAPILLARI
  • [45] Schmickler W., 1996, INTERFACIAL ELECTROC
  • [46] The determination of standard Gibbs energies of transfer of cations across the nitrobenzene|water interface using a three-phase electrode
    Scholz, F
    Gulaboski, R
    Caban, K
    [J]. ELECTROCHEMISTRY COMMUNICATIONS, 2003, 5 (11) : 929 - 934
  • [47] Scholz F, 1998, ELECTROANAL CHEM, V20, P1
  • [48] Electrochemically driven ion insertion processes across liquid/liquid boundaries:: Neutral versus ionic redox liquids
    Schröder, U
    Compton, RG
    Marken, F
    Bull, SD
    Davies, SG
    Gilmour, S
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (07): : 1344 - 1350
  • [49] Scanning electrochemical microscopy (SECM) of facilitated ion transfer at the liquid/liquid interface
    Shao, YH
    Mirkin, MV
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1997, 439 (01): : 137 - 143
  • [50] Microelectrochemical measurements at expanding droplets (MEMED): Mass-transport characterization and assessment of amperometric and potentiometric electrodes as concentration boundary layer probes of liquid/liquid interfaces
    Slevin, CJ
    Unwin, PR
    [J]. LANGMUIR, 1999, 15 (21) : 7361 - 7371
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