Electrifying interfaces

被引：5
作者：
Marken, F [1 ]
机构：
[1] Univ Loughborough, Dept Chem, Loughborough LE11 3TU, Leics, England
来源：
PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES | 2004年 / 362卷 / 1825期
关键词：
electrochemistry; charged phase boundaries; ion transfer; triple junctions; electrosynthesis; tunnelling;
D O I：
10.1098/rsta.2004.1461
中图分类号：
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号：
07 ; 0710 ; 09 ;
摘要：
Electrochemical processes at electrified or polarized phase boundaries and methods for charging phase boundaries are discussed. An important type of interface, the three-phase junction, is introduced and processes at three-phase junctions are compared with those occurring at two-phase functions. Finally, pairing charged interfaces is considered as a methodology for a more efficient use of electrical energy in microscale electrochemical processes. Chemical processes triggered by currents in the ultimate type of paired electrode system. a tunnel junction, are discussed.
引用
收藏
页码：2611 / 2633
页数：23
相关论文
共 62 条
  • [21] THEORY AND EXPERIMENT FOR THE COLLECTOR-GENERATOR TRIPLE-BAND ELECTRODE
    FOSSET, B
    AMATORE, C
    BARTELT, J
    WIGHTMAN, RM
    [J]. ANALYTICAL CHEMISTRY, 1991, 63 (14) : 1403 - 1408
  • [22] GIRAULT HH, 1993, MOD ASPECT ELECTROC, V15, P2
  • [23] Electrochemical analysis of solids.: A review
    Grygar, T
    Marken, F
    Schröder, U
    Scholz, F
    [J]. COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 2002, 67 (02) : 163 - 208
  • [24] Lipophilicity of peptide anions: An experimental data set for lipophilicity calculations
    Gulaboski, R
    Scholz, F
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (23) : 5650 - 5657
  • [25] Formation of mesoscopic silver particles at micro- and nano-liquid/liquid interfaces
    Guo, JD
    Tokimoto, T
    Othman, R
    Unwin, PR
    [J]. ELECTROCHEMISTRY COMMUNICATIONS, 2003, 5 (12) : 1005 - 1010
  • [26] Light emission from organic molecules on metal substrates induced by tunneling currents
    Guo, XL
    Dong, ZC
    Trifonov, AS
    Yokoyama, S
    Mashiko, S
    Okamoto, T
    [J]. JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 2003, 42 (11): : 6937 - 6940
  • [27] Inducing all steps of a chemical reaction with the scanning tunneling microscope tip: Towards single molecule engineering
    Hla, SW
    Bartels, L
    Meyer, G
    Rieder, KH
    [J]. PHYSICAL REVIEW LETTERS, 2000, 85 (13) : 2777 - 2780
  • [28] Engineering of single molecules with a scanning tunneling microscope tip
    Hla, SW
    Rieder, KH
    [J]. SUPERLATTICES AND MICROSTRUCTURES, 2002, 31 (01) : 63 - 72
  • [29] NUCLEOPHILIC AROMATIC-SUBSTITUTION BY PAIRED ELECTROSYNTHESIS - REACTIONS OF METHOXY ARENES WITH 1H-TETRAZOLES
    HU, K
    NIYAZYMBETOV, ME
    EVANS, DH
    [J]. TETRAHEDRON LETTERS, 1995, 36 (39) : 7027 - 7030
  • [30] Jalbout AF, 2002, ACTA CHIM SLOV, V49, P917
1234567