Electrifying interfaces

被引：5

作者：

Marken, F ^{[1
]}

机构：

[1] Univ Loughborough, Dept Chem, Loughborough LE11 3TU, Leics, England

来源：

PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES | 2004年 / 362卷 / 1825期

关键词：

electrochemistry; charged phase boundaries; ion transfer; triple junctions; electrosynthesis; tunnelling;

D O I：

10.1098/rsta.2004.1461

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

Electrochemical processes at electrified or polarized phase boundaries and methods for charging phase boundaries are discussed. An important type of interface, the three-phase junction, is introduced and processes at three-phase junctions are compared with those occurring at two-phase functions. Finally, pairing charged interfaces is considered as a methodology for a more efficient use of electrical energy in microscale electrochemical processes. Chemical processes triggered by currents in the ultimate type of paired electrode system. a tunnel junction, are discussed.

引用

页码：2611 / 2633

页数：23

共 62 条

[11] The relationship between the electrochemistry and the crystallography of microcrystals. The case of TCNQ (7,7,8,8-tetracyanoquinodimethane)
Bond, AM
Fletcher, S
Symons, PG
[J]. ANALYST, 1998, 123 (10) : 1891 - 1904
[12] MECHANISTIC ASPECTS OF THE ELECTRON AND ION-TRANSPORT PROCESSES ACROSS THE ELECTRODE SOLID SOLVENT (ELECTROLYTE) INTERFACE OF MICROCRYSTALLINE DECAMETHYLFERROCENE ATTACHED MECHANICALLY TO A GRAPHITE ELECTRODE
BOND, AM
MARKEN, F
[J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1994, 372 (1-2): : 125 - 135
[13] Unusually fast electron and anion transport processes observed in the oxidation of "electrochemically open" microcrystalline [{M(bipy)2}{M′(bipy)2}(μ-L)](PF6)2 complexes (M, M′ = Ru, Os; bipy=2,2′-bipyridyl; L=1,4-dihydroxy-2,5-bis(pyrazol-1-yl)benzene dianion) at a solid-electrode-aqueous electrolyte interface
Bond, AM
Marken, F
Williams, CT
Beattie, DA
Keyes, TE
Forster, RJ
Vos, JG
[J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (09) : 1977 - 1983
[14] Electrochemical and X-ray diffraction study of the redox cycling of nanocrystals of 7,7,8,8-tetracyanoquinodimethane - Observation of a solid-solid phase transformation controlled by nucleation and growth
Bond, AM
Fletcher, S
Marken, F
Shaw, SJ
Symons, PG
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1996, 92 (20): : 3925 - 3933
[15] Standard partition coefficients of anionic drugs in the n-octanol/water system determined by voltammetry at three-phase electrodes
Bouchard, G
Galland, A
Carrupt, PA
Gulaboski, R
Mirceski, V
Scholz, F
Girault, HH
[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2003, 5 (17) : 3748 - 3751
[16] BRAININA K, 1993, ELECTROANALYTICAL ST
[17] Electrodeposition of metallic gold clusters at the water/1,2-dichloroethane interface
Cheng, YF
Schiffrin, DJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1996, 92 (20): : 3865 - 3871
[18] Sonoelectrochemical processes: A review
Compton, RG
Eklund, JC
Marken, F
[J]. ELECTROANALYSIS, 1997, 9 (07) : 509 - 522
[19] DAVIES TJ, 2004, IN PRESS J ELECTROAN
[20] Coplanar interdigitated band electrodes for electrosynthesis. Part 5: finite element simulation of paired reactions
Ferrigno, R
Josserand, J
Brevet, PF
Girault, HH
[J]. ELECTROCHIMICA ACTA, 1998, 44 (04) : 587 - 595

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