Electrifying interfaces

被引:5
作者
Marken, F [1 ]
机构
[1] Univ Loughborough, Dept Chem, Loughborough LE11 3TU, Leics, England
来源
PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES | 2004年 / 362卷 / 1825期
关键词
electrochemistry; charged phase boundaries; ion transfer; triple junctions; electrosynthesis; tunnelling;
D O I
10.1098/rsta.2004.1461
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Electrochemical processes at electrified or polarized phase boundaries and methods for charging phase boundaries are discussed. An important type of interface, the three-phase junction, is introduced and processes at three-phase junctions are compared with those occurring at two-phase functions. Finally, pairing charged interfaces is considered as a methodology for a more efficient use of electrical energy in microscale electrochemical processes. Chemical processes triggered by currents in the ultimate type of paired electrode system. a tunnel junction, are discussed.
引用
收藏
页码:2611 / 2633
页数:23
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