Detection of Omethoate Residues in Peach with Surface-Enhanced Raman Spectroscopy

被引:65
作者
Yaseen, Tehseen [1 ,2 ,3 ]
Sun, Da-Wen [1 ,2 ,3 ,4 ]
Pu, Hongbin [1 ,2 ,3 ]
Pan, Ting-Tiao [1 ,2 ,3 ]
机构
[1] South China Univ Technol, Sch Food Sci & Engn, Guangzhou 510641, Guangdong, Peoples R China
[2] South China Univ Technol, Guangzhou Higher Educ Mega Ctr, Acad Contemporary Food Engn, Guangzhou 510006, Guangdong, Peoples R China
[3] Guangzhou Higher Educ Mega Ctr, Engn & Technol Res Ctr Guangdong Prov Intelligent, Guangzhou 510006, Guangdong, Peoples R China
[4] Natl Univ Ireland, Univ Coll Dublin, Agr & Food Sci Ctr, Food Refrigerat & Computerized Food Technol FRCFT, Dublin 4, Ireland
基金
国家重点研发计划;
关键词
SERS; Residue detection; Omethoate; Substrate; Fruit; SILVER NANOPARTICLES; PESTICIDE-RESIDUES; CHEMOMETRIC ANALYSIS; CHEMICAL SPOILAGE; MASS-SPECTROMETRY; COMPUTER VISION; RAPID DETECTION; SERS; PREDICTION; QUALITY;
D O I
10.1007/s12161-018-1233-y
中图分类号
TS2 [食品工业];
学科分类号
0832 ;
摘要
In this work, surface-enhanced Raman spectroscopy (SERS) was used with silver colloid substrate for rapid detection of omethoate (an organophosphate pesticide) in standard solution and peach extract. The findings demonstrated that the characteristic wavenumber of the pesticide could be precisely identified using the SERS method. The calibration curve was plotted between concentrations and Raman intensities of the target peak at 1649 cm(-1) for the peach extract and at 1647 cm(-1) for the standard solution. The coefficients of determination (R (2)) of 0.9829 and 0.98 were obtained for standard solution and for peach extract, respectively. The calculated limits of detection for omethoate in standard solution and in peach extracts were 0.001 mg L-1 and 0.01 mg kg(-1), respectively. This study revealed that the proposed method could be used for the analysis of trace contaminants like omethoate in multifaceted food matrices.
引用
收藏
页码:2518 / 2527
页数:10
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