Use of a New Polymer Anchored Cu(II) Azo Complex Catalyst for the Efficient Liquid Phase Oxidation Reactions

被引：33

作者：

Islam, Manirul ^{[1
]}

Mondal, Paramita ^{[1
]}

Mondal, Sanchita ^{[1
]}

Mukherjee, Sanghamitra ^{[1
]}

Roy, Anupam Singha ^{[1
]}

Mubarak, Manir ^{[1
]}

Paul, Manidipa ^{[2
]}

机构：

[1] Univ Kalyani, Dept Chem, Nadia 741235, WB, India

[2] Indian Assoc Cultivat Sci, Dept Mat Sci, Kolkata 700032, India

来源：

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS | 2010年 / 20卷 / 01期

关键词：

Polymer anchored; Cu(II) complex; Oxidation; Olefin and aromatic alcohol; SCHIFF-BASE COMPLEX; COPPER(II) COMPLEXES; HYDROGEN-PEROXIDE; SELECTIVE OXIDATION; ORGANIC-COMPOUNDS; CYCLOHEXENE; MCM-41; NICKEL(II); COBALT(II); LIGANDS;

D O I：

10.1007/s10904-009-9310-8

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A new polymer anchored copper(II) azo complex has been synthesized and characterized by using scanning electron microscope (SEM), thermogravimetric analysis (TGA), elemental analysis, atomic absorption spectroscopy (AAS) and spectrometric methods like diffuse reflectance spectra of solid (DRS) and Fourier transform infrared spectroscopy (FTIR). The immobilized Cu(II) catalyst shows excellent catalytic activity in oxidation of cyclohexene, styrene, benzyl alcohol and ethylbenzene in presence of tert-butylhydroperoxide (TBHP) as an oxidant. The effects of different solvents, oxidants, temperature, substrate oxidant ratio and amount of catalyst were also studied. The catalytic results reveal that the polymer-anchored Cu(II) azo complex catalyst can be recycled more than five times without appreciable loss in the catalytic activity.

引用

页码：87 / 96

页数：10

共 35 条

[1] Selective oxidation of alkenes and alkynes catalyzed by copper complexes [J].