KA2 and A3 coupling reactions promoted by Fe3O4@T-CS@Cys@Ag+ nanocomposite

被引：5

作者：

Rafiee, F. ^{[1
]}

Hosseinvand, S. ^{[1
]}

机构：

[1] Alzahra Univ, Dept Chem, Fac Phys Chem, POB 1993893973, Tehran, Iran

来源：

POLYMER BULLETIN | 2022年 / 79卷 / 05期

关键词：

Functionalized chitosan; Chitosan-supported catalysts; Magnetic nanocatalyst; KA(2) coupling reaction; A(3) coupling reaction; Propargylamines;

D O I：

10.1007/s00289-021-03651-8

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Chitosan biopolymer was functionalized with cysteine amino acid via trichloro-1,3,5-triazine-bridged agent. The magnetization process was done due to the treatment of functionalized chitosan with iron oxide nanoparticles. In the final nanocomposite (Fe3O4@T-CS@Cys@Ag+), thiol and carboxylate groups of cysteine were surrounded by silver ions. The catalytic activity of the prepared nanocomposite was studied in KA(2) and A(3) coupling reactions for the synthesis of propargylamines.

引用

页码：2799 / 2817

页数：19

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