The crystal and molecular structure of a trifluoroacetylacetonate complex of scandium, Sc(CH3COCHCOCF3)3

被引：5

作者：

Bennett, Dennis W.

Siddiquee, Tasneem A.

Haworth, Daniel T.

Lindeman, Sergey V.

机构：

[1] Univ Wisconsin, Dept Chem, Milwaukee, WI 53211 USA

[2] Marquette Univ, Dept Chem, Milwaukee, WI 53201 USA

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2007年 / 37卷 / 03期

关键词：

trifluoroacetylactonate; scandium acac; dipole moment;

D O I：

10.1007/s10870-006-9171-8

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The crystal and molecular structure of Sc(CH3COCHCOCF3)(3) has been determined by X-ray diffraction. The compound crystallizes as pure mer-isomer in the orthorhombic space group Pbca with lattice parameters a=15.166(8) angstrom, b=13.560(7) angstrom, c=19.327(10) angstrom, alpha=beta=gamma=90 degrees, V=3974(4) angstrom(3), Z=8. The complex at 100 K is partially disordered in the crystal structure in an approximate 5:1 ratio with 83% fluorine population at C-11 and 17% at C-15. NMR data is compared to that previously reported.

引用

页码：207 / 212

页数：6

共 8 条

[1] COORDINATION CHEMISTRY OF SCANDIUM .5. CRYSTAL AND MOLECULAR-STRUCTURE OF TRIS(ACETYLACETONATO)SCANDIUM(III) [J].