Co-MOF Nanosheet Arrays for Efficient Alkaline Oxygen Evolution Electrocatalysis

被引:43
作者
Yu, Jin [1 ]
Cao, Yang [2 ]
Liu, Qian [3 ]
Luo, Yonglan [3 ]
Liu, Yang [4 ]
Shi, Xifeng [5 ]
Asiri, Abdullah M. [6 ,7 ]
Li, Tingshuai [1 ]
Sun, Xuping [2 ]
机构
[1] Univ Elect Sci & Technol China, Sch Mat & Energy, Chengdu 611731, Sichuan, Peoples R China
[2] Univ Elect Sci & Technol China, Inst Fundamental & Frontier Sci, Chengdu 610054, Sichuan, Peoples R China
[3] Chengdu Univ, Inst Adv Study, Chengdu 610106, Sichuan, Peoples R China
[4] Henan Normal Univ, Sch Mat Sci & Engn, Xinxiang 453007, Henan, Peoples R China
[5] Shandong Normal Univ, Coll Chem Chem Engn & Mat Sci, Jinan 250014, Shandong, Peoples R China
[6] King Abdulaziz Univ, Fac Sci, Dept Chem, POB 80203, Jeddah 21589, Saudi Arabia
[7] King Abdulaziz Univ, Ctr Excellence Adv Mat Res, POB 80203, Jeddah 21589, Saudi Arabia
关键词
Co-MOF nanosheet arrays; nickel foam; water oxidation; alkaline reaction; WATER OXIDATION ELECTROCATALYSIS; METAL-ORGANIC FRAMEWORK; BIFUNCTIONAL ELECTROCATALYST; NANOWIRE ARRAY; NI FOAM;
D O I
10.1002/cnma.202100153
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
It's highly desirable to devise and develop non-precious metal catalysts for efficient water oxidation catalysis in alkaline solution. Herein, we report Co-MOF nanosheet arrays grown on the three dimensional conductive nickel foam (Co-MOF/NF) through a hydro-thermal process for efficient alkaline oxygen evolution electrocatalysis. Such catalyst displays an excellent electrochemical performance by achieving an overpotential of 290 mV at 20 mA cm(-2) in 1.0 M KOH. Besides, it possesses both a good electrochemical stability and a high turnover frequency of 0.14 s(-1) at the overpotential of 400 mV.
引用
收藏
页码:906 / 909
页数:4
相关论文
共 45 条
[41]   An Fe-MOF nanosheet array with superior activity towards the alkaline oxygen evolution reaction [J].
Zhang, Xiaoxue ;
Liu, Qin ;
Shi, Xifeng ;
Asiri, Abdullah M. ;
Sun, Xuping .
INORGANIC CHEMISTRY FRONTIERS, 2018, 5 (06) :1405-1408
[42]   Shaping of ultrahigh-loading MOF pellet with a strongly anti-tearing binder for gas separation and storage [J].
Zheng, Jieyi ;
Cui, Xili ;
Yang, Qiwei ;
Ren, Qilong ;
Yang, Yiwen ;
Xing, Huabin .
CHEMICAL ENGINEERING JOURNAL, 2018, 354 :1075-1082
[43]   Iron-substituted Co-Ni phosphides immobilized on Ni foam as efficient self-supported 3D hierarchical electrocatalysts for oxygen evolution reaction [J].
Zhou, Chenmin ;
Mu, Jianshuai ;
Qi, Yu-Feng ;
Wang, Qian ;
Zhao, Xiao-Jun ;
Yang, En-Cui .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2019, 44 (16) :8156-8165
[44]   Co3O4 Nanowire Arrays toward Superior Water Oxidation Electrocatalysis in Alkaline Media by Surface Amorphization [J].
Zhou, Dan ;
He, Liangbo ;
Zhang, Rong ;
Hao, Shuai ;
Hou, Xiandeng ;
Liu, Zhiang ;
Du, Gu ;
Asiri, Abdullah M. ;
Zheng, Chengbin ;
Sun, Xuping .
CHEMISTRY-A EUROPEAN JOURNAL, 2017, 23 (62) :15601-15606
[45]   Design and Application of Foams for Electrocatalysis [J].
Zhu, Wenxin ;
Zhang, Rong ;
Qu, Fengli ;
Asiri, Abdullah M. ;
Sun, Xuping .
CHEMCATCHEM, 2017, 9 (10) :1721-1743