Gas-phase dehydration of glycerol over hierarchical silicoaluminophosphate SAPO-40

被引：19

作者：

Fernandes, Auguste ^{[1
]}

Filipa Ribeiro, M. ^{[1
]}

Lourenco, Joao P. ^{[1
,2
]}

机构：

[1] Univ Lisbon, Inst Super Tecn, Ctr Quim Estrutural, Av Rovisco Pais, P-1096001 Lisbon, Portugal

[2] Univ Algarve, CIQA, Fac Ciencias & Tecnol, Campus Gambelas, P-8005139 Faro, Portugal

来源：

CATALYSIS COMMUNICATIONS | 2017年 / 95卷

关键词：

Hierarchical; SAPO-40; Glycerol dehydration; Acrolein; Sustainable chemistry; SURFACTANT-DIRECTED SYNTHESIS; HYDROTHERMAL STABILITY; SUSTAINABLE PRODUCTION; ACROLEIN; CATALYSTS; PERFORMANCE; CONVERSION; ZEOLITES; POROSITY;

D O I：

10.1016/j.catcom.2017.02.015

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Hierarchical silicoaluminophosphate SAPO-40 was synthetized using an organosilane acting as additional porogen agent. The structural, textural and acid properties of the new material were evaluated using XRD, Si-29 and Al-27 MAS NMR, SEM, N-2 adsorption, pyridine adsorption followed by IR spectroscopy and thermal analyses. The evaluation of the catalytic performance in the dehydration of glycerol has evidenced a high activity and a very low deactivation rate. When compared with the conventional SAPO-40, this catalyst shows higher acrolein selectivity and a significantly longer catalytic lifetime. (C) 2017 Elsevier B.V. All rights reserved.

引用

页码：16 / 20

页数：5