Coordination-driven self-assembly in a single pot

被引：18

作者：

Debata, Niladri B. ^{[1
]}

Tripathy, Debakanta ^{[1
]}

Ramkumar, V. ^{[1
]}

Chand, Dillip Kumar ^{[1
]}

机构：

[1] Indian Inst Technol Madras, Dept Chem, Madras 600036, Tamil Nadu, India

来源：

TETRAHEDRON LETTERS | 2010年 / 51卷 / 33期

关键词：

Palladium; Self-assembly; One-pot synthesis; Molecular rhombus; POLYGONS; SYMMETRY; TRIANGLE; CRYSTAL;

D O I：

10.1016/j.tetlet.2010.06.084

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

New multinuclear discrete heteroleptic complexes have been synthesized by mixing Pd(II), and N,N'-(1,2-phenylene)diisonicotinamide in a single pot as a new approach A dimeric molecular rhombus and a trimer in equilibrium are obtained where the dimer is the major product Similar equilibrium is also observed when classical method is employed for the synthesis The equilibrium is shifted exclusively in favour of the dimer upon addition of benzene The complexes are characterized by NMR and ESI-MS methods Crystal structure of the benzene encapsulated rhombus is presented (C) 2010 Elsevier Ltd All rights reserved

引用

页码：4449 / 4451

页数：3

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