Hosomi-Sakurai reactions of silacyclohexenes

被引：17
|
作者：
Hughes, Nicholas J.
Pullin, Robert D. C.
Sanganee, Mahesh J.
Sellars, Jonathan D.
Steel, Patrick. G.
Turner, Michael J.
机构：
[1] Univ Durham, Dept Chem, Sci Labs, Durham DH1 3LE, England
[2] GlaxoSmithKline, Stevenage SG1 2NY, Herts, England
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2007年 / 5卷 / 17期
关键词：
D O I：
10.1039/b709318g
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Silacyclic allyl silanes, derived from silene-diene Diels-Alder reactions, combine with acetals in the presence of Lewis acids to afford, following oxidation of the intermediate fluorosilane, either butane-1,4-diols or tetrahydronaphthalenes containing four contiguous chiral centres with moderate to good diastereoselectivity.
引用
收藏
页码：2841 / 2848
页数：8
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